IP Library Granted Patent US 9,499,772
Granted Patent B2
US 9,499,772 · App. 13/801,493 · Granted Nov 22, 2016

Methods of decontaminating surfaces and related compositions

Inventors: Ricky L. Demmer (Idaho Falls, ID); Daniel Crosby (Keene, NH); Christopher J. Norton (Spofford, NH)
Assignee: BATTELLE ENERGY ALLIANCE, LLC
C11D3/32B08B3/08B08B3/12C11D1/28C11D3/042C11D3/046C11D3/048C11D3/065C11D3/222C11D3/26G21F9/002G21F9/162G21F9/167
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Quick Facts
Patent No.
US 9,499,772
App. No.
13/801,493
Granted
Nov 22, 2016
Kind
B2
Abstract

A composition of matter includes water, at least one acid, at least one surfactant, at least one fluoride salt, and ammonium nitrate. A method of decontaminating a surface includes exposing a surface to such a composition and removing the composition from the surface. Other compositions of matter include water, a fatty alcohol ether sulfate, nitrilotriacetic acid, at least one of hydrochloric acid and nitric acid, sodium fluoride, potassium fluoride, ammonium nitrate, and gelatin.

Claims (69)

1. A composition, comprising:

water;

at least one chelator selected from the group consisting of ethylenediaminetetraacetic acid, (2-hydroxyethyl)ethylenediaminetriacetic acid, ethylene glycol-bis-(2-aminoethyl)-tetracetic acid, ammonium molybdophosphate, and nitrilotriacetic acid;

at least one of hydrochloric acid or nitric acid;

at least one surfactant comprising a fatty alcohol ether sulfate;

at least one fluoride salt; and

ammonium nitrate.

2. The composition of claim 1 , further comprising gelatin.

3. The composition of claim 1 , further comprising corn starch.

4. The composition of claim 1 , wherein the fatty alcohol ether sulfate comprises at least one of a sodium salt of the fatty alcohol ether sulfate or an ammonium salt of the fatty alcohol ether sulfate.

5. The composition of claim 1 , wherein the at least one surfactant is present at from about 0.1% by weight to about 10% by weight.

6. The composition of claim 1 , wherein:

the at least one chelator comprises nitrilotriacetic acid; and

the at least one fluoride salt comprises at least one of sodium fluoride or potassium fluoride.

7. The composition of claim 6 , further comprising gelatin.

8. The composition of claim 6 , further comprising corn starch.

9. The composition of claim 1 , wherein:

the water comprises from about 40% by weight to about 50% by weight of the composition;

the at least one chelator comprises from about 4% by weight to about 60% by weight of the composition;

the at least one surfactant comprises from about 0.1% by weight to about 10% by weight of the composition;

the at least one fluoride salt comprises from about 0.1% by weight to about 10% by weight of the composition; and

the ammonium nitrate comprises from about 0.05% by weight to about 5.0% by weight of the composition.

10. The composition of claim 1 , wherein the composition comprises water, nitrilotriacetic acid, hydrochloric acid, ammonium molybdophosphate, the fatty alcohol ether sulfate, sodium fluoride, potassium fluoride, and ammonium nitrate.

11. The composition of claim 1 , wherein the composition comprises water, nitrilotriacetic acid, citric acid, hydrochloric acid, ammonium molybdophosphate, the fatty alcohol ether sulfate, sodium fluoride, potassium fluoride, and ammonium nitrate.

12. The composition of claim 1 , wherein the pH of the composition is between about -0.5 and about 5.

13. The composition of claim 1 , wherein the composition is formulated to generate a foam.

14. The composition of claim 1 , wherein a pH of the composition is less than about 6.

15. A composition, comprising:

water;

a fatty alcohol ether sulfate;

nitrilotriacetic acid;

hydrochloric acid;

sodium fluoride;

potassium fluoride;

ammonium nitrate; and

gelatin.

16. The composition of claim 15 , further comprising corn starch, citric acid, and ammonium molybdophosphate.

17. The composition of claim 15 , wherein the composition comprises from about 0.03% by weight to about 1% by weight of nitrilotriacetic acid.

18. The composition of claim 15 , wherein the composition comprises from about 20% by weight to about 35% by weight of hydrochloric acid.

19. A composition consisting essentially of:

water;

a fatty alcohol ether sulfate;

nitrilotriacetic acid;

hydrochloric acid;

sodium fluoride;

corn starch;

citric acid;

ammonium nitrate;

potassium fluoride;

ammonium molybdophosphate; and

gelatin.

20. A method of decontaminating a surface, comprising:

exposing a surface to a composition, the surface having a radioactive contaminant material thereon and the composition comprising:

water;

at least one acid;

at least one surfactant;

at least one fluoride salt; and

ammonium nitrate; and

removing at least a portion of the composition from the surface to remove at least a portion of the radioactive contaminant material from the surface.

21. The method of claim 20 , wherein removing at least a portion of the radioactive contaminant material from the surface further comprises removing biological contaminant materials or chemical contaminant materials from the surface.

22. The method of claim 20 , further comprising applying ultrasonic energy to the composition.

23. The method of claim 20 , further comprising injecting a gas into the composition to produce a foam before exposing the surface to the composition.

24. The method of claim 20 , wherein exposing the surface to a composition comprises exposing the surface to a composition comprising water, a fatty alcohol ether sulfate, nitrilotriacetic acid, hydrochloric acid, sodium fluoride, potassium fluoride, and ammonium nitrate.

25. The method of claim 20 , wherein exposing a surface to a composition comprises exposing the surface to a composition wherein:

the water comprises from about 40% by weight to about 50% by weight of the composition;

the at least one acid comprises from about 20% by weight to about 60% by weight of the composition;

the at least one surfactant comprises from about 0.1% by weight to about 10% by weight of the composition;

the at least one fluoride salt comprises from about 0.1% by weight to about 10% by weight of the composition; and

the ammonium nitrate comprises from about 0.05% by weight to about 5.0% by weight of the composition.

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 25, 2016
From: NORTON, CHRISTOPHER J.
To: ENVIRONMENTAL ALTERNATIVES, INC.
Reel/Frame 040120/0021 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 25, 2016
From: CROSBY, DANIEL J
To: ENVIRONMENTAL ALTERNATIVES, INC.
Reel/Frame 040120/0084 →
CONFIRMATORY LICENSE Recorded Jan 27, 2014
From: BATTELLE ENERGY ALLIANCE, LLC
To: ENERGY, UNITED STATES DEPARTMENT OF
Reel/Frame 032112/0103 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 19, 2013
From: DEMMER, RICKY L.
To: BATTELLE ENERGY ALLIANCE, LLC
Reel/Frame 030044/0987 →
Continuity (1)
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