Plugged honeycomb structure
There is disclosed a plugged honeycomb structure. A plugged honeycomb structure includes a pillar-shaped honeycomb structure body having porous partition walls defining a plurality of cells which become through channels for a fluid and extend from a first end face to a second end face, and plugging portions disposed in open ends of predetermined cells in the first end face and open ends of residual cells in the second end face, and the partition walls are constituted of a porous body including α-Al 2 O 3 as a main phase and further including aluminum titanate and glass.
1. A plugged honeycomb structure comprising:
a pillar-shaped honeycomb structure body having porous partition walls defining a plurality of cells which become through channels for a fluid and extend from a first end face to a second end face; and
plugging portions disposed in open ends of the predetermined cells in the first end face and open ends of the residual cells in the second end face,
wherein the partition walls are constituted of a porous body including α-Al 2 O 3 as a main phase and further including aluminum titanate and glass.
2. The plugged honeycomb structure according to claim 1 ,
wherein a mass ratio between the α-Al 2 O 3 and the aluminum titanate in the porous body is from 60/40 to 90/10.
3. The plugged honeycomb structure according to claim 2 ,
wherein the porous body includes 5 to 15 mass % of the glass to 100 mass % in total of the α-Al 2 O 3 , the aluminum titanate and the glass.
4. The plugged honeycomb structure according to claim 1 ,
wherein in the porous body, at least one selected from a first group consisting of Fe, Mg and Si is solid-dissolved in the aluminum titanate.
5. The plugged honeycomb structure according to claim 4 ,
wherein a mass ratio of each of Fe 2 O 3 , MgO and SiO 2 obtained by oxide conversion of Fe, Mg and Si among solid-solution components included into the aluminum titanate is from 0.1 to 10.0 mass % to a total of masses of Al 2 O 3 and TiO 2 obtained by oxide conversion of Al and Ti included in the aluminum titanate and masses of the components included into the aluminum titanate which are obtained by the oxide conversion.
6. The plugged honeycomb structure according to claim 1 ,
wherein the porous body includes 5 to 15 mass % of the glass to 100 mass % in total of the α-Al 2 O 3 , the aluminum titanate and the glass.
7. The plugged honeycomb structure according to claim 1 ,
wherein the glass includes SiO 2 and Al 2 O 3 .
8. The plugged honeycomb structure according to claim 7 ,
wherein the glass further includes an oxide made of at least one selected from a group consisting of an alkali metal, an alkali earth metal, Ti and Fe.
9. The plugged honeycomb structure according to claim 1 ,
wherein a true density of a material constituting the porous body is from 3.65 to 3.85 g/cm 3 .
10. The plugged honeycomb structure according to claim 1 ,
wherein a heat capacity of the material constituting the porous body at 600° C. is from 4.25 to 4.50 J/K/cm 3 .
11. The plugged honeycomb structure according to claim 10 ,
wherein an average thermal expansion coefficient of the porous body at 40 to 800° C. is from 2.5 to 6.0 ppm/K, and
wherein the porous body satisfies a relation of the following equation (1):
C− 0.007×α 2 ≧4.20 (1),
in which C is a heat capacity (J/K/cm 3 ) of the material constituting the porous body at 600° C. and α is an average thermal expansion coefficient (ppm/K) of the porous body at 40 to 800° C.
12. The plugged honeycomb structure according to claim 1 ,
wherein an average thermal expansion coefficient of the porous body at 40 to 800° C. is from 2.5 to 6.0 ppm/K.
13. The plugged honeycomb structure according to claim 1 ,
wherein the porous body satisfies a relation of the following equation (1):
C− 0.007×α 2 ≧4.20 (1),
in which C is a heat capacity (J/K/cm 3 ) of the material constituting the porous body at 600° C. and α is an average thermal expansion coefficient (ppm/K) of the porous body at 40 to 800° C.
14. The plugged honeycomb structure according to claim 1 ,
wherein a porosity of the porous body is from 20 to 50%.
15. The plugged honeycomb structure according to claim 1 ,
wherein an average pore diameter of the porous body is from 5 to 20 μm.
16. The plugged honeycomb structure according to claim 1 ,
wherein the honeycomb structure body is a segmented structure which has a plurality of pillar-shaped honeycomb segments having the partition walls and in which the plurality of honeycomb segments are bonded in a state where the honeycomb segments are disposed adjacent to one another so that side surfaces of the honeycomb segments face one another.
17. The plugged honeycomb structure according to claim 1 ,
wherein an exhaust gas purifying catalyst is loaded onto at least one of each surface of the partition walls of the honeycomb structure body and each pore of the partition walls.