PET nonwoven fabric for separator for secondary battery and separator for secondary battery comprising the same
A PET nonwoven fabric for a separator for a secondary battery includes first fibers composed of PET having a melting temperature of 240° C. or more and second fibers composed of PET having a melting temperature of 180˜220° C., respective fibers having two types of fibers having different diameters, and has a fine pore size and uniform pore distribution and exhibits superior surface properties, low surface defects, high mechanical strength and excellent mass production. Even when the temperature of a battery is increased to 200° C. or more, the PET nonwoven fabric has heat resistance which prevents thermal runaway and does not generate melting and shrinking.
1. A polyethyleneterephthalate (PET) nonwoven fabric for a separator for secondary battery, comprising first fibers comprising PET having a melting temperature of 240° C. or more and second fibers comprising PET having a melting temperature of 180˜220° C.,
wherein the first fibers have an aspect ratio of 500˜2000, and include two types of fibers comprising fibers (i) having a diameter ranging from 0.7 μm to less than 2.3 μm and fibers (ii) having a diameter ranging from 2.3 μm to 5.5 μm, and
the second fibers have an aspect ratio of 500˜2000, and include fibers (iii) having a diameter ranging from 2.0 μm to less than 4.3 μm, and fibers (iv) having a diameter ranging from 4.3 μm to 7.0 μm.
2. The PET nonwoven fabric of claim 1 , comprising, based on a total weight of the nonwoven fabric, 40˜70 wt % of the first fibers and 30˜60 wt % of the second fibers.
3. The PET nonwoven fabric of claim 1 , wherein an amount ratio of the fibers (i) to the fibers (ii) in the first fibers is 95:5˜5:95.
4. The PET nonwoven fabric of claim 1 , wherein an amount ratio of the fibers (iii) to the fibers (iv) in the second fibers is 90:10˜10:90.
5. The PET nonwoven fabric of claim 1 , wherein the PET nonwoven fabric has a porosity of 45˜85% and an average pore diameter of 0.5˜7.0 μm.
6. The PET nonwoven fabric of claim 1 , wherein the PET nonwoven fabric has a punching strength of 200˜600 gf and a tensile strength of 250˜1500 kgf/cm 2 .
7. The PET nonwoven fabric of claim 1 , which is provided in a form of a monolayer or a multilayer of two or more layers.
8. The PET nonwoven fabric of claim 7 , wherein the nonwoven fabric has a total thickness of 10˜45 μm, and when the nonwoven fabric is provided in a multilayer form, a thickness of each layer of the multilayer exceeds at least 6.0 μm.
9. The PET nonwoven fabric of claim 7 , which has a double layer structure wherein each layer has a thickness from more than 6 μm to 20 μm.
10. A separator for a secondary battery, comprising the PET nonwoven fabric of claim 1 , and a nanofiber layer formed on one or both surfaces thereof and comprising nanofibers having a diameter of 100˜600 nm.
11. The separator of claim 10 , wherein the nanofibers have a melting temperature of 120˜170° C.
12. The separator of claim 11 , wherein the nanofibers comprise any one selected from among polytetrafluoroethylene (PTFE), polychlorotrifluoroethylene (PCTFE), polyvinylidenefluoride (PVDF), polyvinylidenefluoride-hexafluoropropylene (PVDF-HFP), polyvinylfluoride (PVF), polyimide, and aramid.
13. The separator of claim 10 , wherein a thickness of the nanofiber layer is 10˜30% of that of the PET nonwoven fabric which is a substrate layer.
14. The separator of claim 10 , wherein the separator has a porosity of 40˜80% and an average pore diameter of 0.1˜1.0 μm.
15. The separator of claim 10 , wherein the separator has a punching strength of 200˜600 gf and a tensile strength of 250˜1500 kgf/cm 2 .
16. The separator of claim 10 , wherein the secondary battery is a lithium secondary battery.