Negative electrode composition for rechargeable lithium battery, negative electrode comprising same and rechargeable lithium battery comprising same
A negative electrode composition for a rechargeable lithium battery. The negative electrode includes a negative active material and crystalline carbon conductive material, wherein the negative active material includes soft carbon, and the crystalline carbon conductive material includes graphite having an average particle diameter (D90) of about 1 micrometer to about 20 micrometers.
1. A negative electrode composition for a rechargeable lithium battery, the negative electrode composition comprising:
a negative active material and a crystalline carbon conductive material,
wherein:
the negative active material comprises soft carbon, the soft carbon has a (500) peak at 2θ of about 25°, a (8700) peak at 2θ of about 43°, a (7100) peak at 2θ of about 50° and a (1300) peak at 2 θ of about 74° in X-ray diffraction (XRD) analysis; and
the crystalline carbon conductive material comprises graphite having an average particle diameter (D90) of about 1 micrometer to about 20 micrometers.
2. The negative electrode composition of claim 1 , wherein the crystalline carbon conductive material is included in an amount of about 0.5 wt % to about 45.5 wt % based on the total amount of the negative electrode composition.
3. The negative electrode composition of claim 1 , wherein the crystalline carbon conductive material is included in an amount of about 0.5 wt % to about 25 wt % based on the total amount of the negative electrode composition.
4. The negative electrode composition of claim 1 , wherein the crystalline carbon conductive material is an anisometric flake material.
5. The negative electrode composition of claim 1 , wherein the crystalline carbon conductive material has a scott density of less than or equal to about 0.2 g/cm 3 .
6. The negative electrode composition of claim 1 , wherein the crystalline carbon conductive material has a specific surface area of about 5 to about 30m 2 /g .
7. The negative electrode composition of claim 1 , wherein the crystalline carbon conductive material has a dibutylphthalate (DBP) absorption of about 100 to about 300 g/100g.
8. The negative electrode composition of claim 1 , wherein the crystalline carbon conductive material comprises ash in an amount of less than or equal to about 0.1 wt % based on the total amount of the crystalline carbon conductive material.
9. The negative electrode composition of claim 1 , wherein the crystalline carbon conductive material further comprises carbon black.
10. The negative electrode composition of claim 1 , wherein the crystalline carbon conductive material has a (14700) peak at 2θ of about 26° in X-ray diffraction (XRD) analysis.
11. The negative electrode composition of claim 1 , further comprising a binder.
12. The negative electrode composition of claim 11 , wherein the binder is selected from carboxylmethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose, polyvinylidene fluoride, polytetrafluoroethylene, polyethylene, polypropylene, a styrene-butadiene rubber, a polybutadiene, a butyl rubber, a fluorine rubber, polyethyleneoxide, polyvinylalcohol, poly(metha)acrylic acid and a salt thereof, polyvinylpyrrolidone, polyepichlorohydrin, polyphosphazene, polyacrylonitrile, polystyrene, polyvinylpyridine, chlorosulfonated polyethylene, a latex, a polyester resin, an acrylic resin, a phenolic resin, an epoxy resin, a polymer of propylene and C2 to C8 olefin, a copolymer of (meth)acrylic acid and (meth)acrylic acid alkyl ester, and combinations thereof.
13. A negative electrode for a rechargeable lithium battery, the negative electrode comprising:
a current collector, and
the negative electrode composition on the current collector according to claim 1 .
14. A rechargeable lithium battery, the rechargeable battery comprising:
the negative electrode according to claim 13 ;
a positive electrode comprising a positive active material;
a separator between the positive electrode and the negative electrode; and
an electrolyte.
15. The rechargeable lithium battery of claim 14 , wherein the positive active material comprises at least one selected from a lithium cobalt-based oxide, a lithium nickel cobalt manganese-based oxide, a lithium nickel cobalt aluminum-based oxide, and an olivine-based oxide.
16. The rechargeable lithium battery of claim 15 , wherein the positive active material further comprises activated carbon.
17. The rechargeable lithium battery of claim 16 , wherein the activated carbon is included in an amount of about 0.5 wt % to about 50 wt % based on the total amount of the positive active material.
18. The rechargeable lithium battery of claim 14 , wherein the positive electrode further comprises a conductive material.
19. The rechargeable lithium battery of claim 18 , wherein the conductive material comprises at least one selected from natural graphite, artificial graphite, carbon black, acetylene black, ketjen black, a carbon fiber, a carbon nanotube, a metal powder, a metal fiber, and a conductive polymer.
20. The rechargeable lithium battery of claim 14 , wherein the rechargeable lithium battery is configured as a battery for ISG (integrated starter generator).