Sliding component coated with metal-comprising carbon layer for improving wear and friction behavior by tribological applications under lubricated conditions
The present invention relates to a coating for sliding parts that allows using diamond like carbon (DLC) or DLC-comprising coatings in combination with Molybdenum- and/or Zinc-comprising lubricants in such a manner that enhanced reduction of wear and friction in comparison to the state of the art is attained. The coating system according to the present invention comprises at least a metal-comprising carbon layer of the type Me-C/a)-C:X, whose element composition can be expressed as (Me a C 1-a ) 1-b X b with 0.3≦a≦0.6 and 0<b≦0.3, where Me is a metal or a combination of different metals and X is an element different from Me and different from C or X is a mixture of elements different from Me and which doesn't contain C. Me can be preferably Chromium (Cr) or Molybdenum (Mo) and X can be preferably hydrogen (H) or a mixture of silicon and hydrogen (Si+H).
1. A sliding component for tribological contact under lubricated conditions, the sliding component comprising a coating at least partially in contact with a fluid lubricant, the coating being a metal doping modified DLC coating and comprising one or more function layers having an element composition of (Me a C 1-a ) 1-b X b , 0.3=<a=<0.6, 0<b=<0.3, a being the atomic fraction of Me if only Me and C are considered for the element composition, b being the atomic fraction of X if Me, C, and X are considered for the element composition, Me consisting of materials selected from the group consisting of chromium, molybdenum, and a mixture of two or more metals consisting essentially of one of chromium and molybdenum, C being carbon, X consisting of materials selected from the group consisting of hydrogen, silicon, nitrogen, boron, and a mixture of elements consisting essentially of one or more of the group consisting of hydrogen, silicon, nitrogen, and boron, the fluid lubricant comprising one of molybdenum, zinc, and a combination thereof,
wherein Me:C ratio ranges from about 40% up to about 60%.
2. The sliding component according to claim 1 , wherein Me consists of chromium and X consists of hydrogen.
3. The sliding component according to claim 1 , wherein Me consists of chromium and X consists of a mixture of hydrogen and silicon.
4. The sliding component according to claim 1 , wherein a is about 0.45.
5. The sliding component according to claim 4 , wherein Me consists of chromium and X consists of hydrogen.
6. The sliding component according to claim 1 , wherein the coating further comprises one or more layers selected from the group consisting of one or more adhesion layers, one or more support layers, one or more transition layers, and one or more run-in layers,
wherein, if the coating comprises the adhesion layers, the adhesion layers are deposited on a substrate surface to be coated between the substrate surface to be coated and the function layers,
wherein, if the coating comprises the support layers and the adhesion layers, the support layers are deposited under the function layers and one of between the substrate surface to be coated and the function layers and between the adhesion layers and the function layers,
wherein, if the coating comprises the transition layers, the adhesion layers, and the support layers, the transition layers are deposited under the function layers and one of between the adhesion layers and the function layers and between the support layers and the function layers, and
wherein, if the coating comprises the run-in layers, the run-in layers are deposited above the function layers.
7. The sliding component according to claim 6 , wherein Me consists of chromium and X consists of hydrogen.
8. The sliding component according to claim 6 , wherein Me is chromium and X is a mixture of hydrogen and silicon.
9. The sliding component according to claim 6 , wherein a is about 0.45.
10. The sliding component according to claim 9 , wherein Me is chromium and X is hydrogen.
11. The sliding component according to claim 6 , wherein Me consists of chromium, and
wherein one of:
if the coating comprises the adhesion layers, one or more of the adhesion layers have a thickness that is less than 1 micron and consists essentially of a metallic layer consisting of chromium;
if the coating comprises the support layers, one or more of the support layers consists essentially of chromium nitride;
if the coating comprises the transition layers and the support layers, each of the transition layers consists essentially a metal-carbon-nitrogen layer comprising Me and X, the metal-carbon-nitrogen layer being a gradient layer having a variable concentration of elements along a thickness of the gradient layer, the carbon concentration of the gradient layer being at its lowest when near the support layers and its highest when near the functional layers;
if the coating comprises the run-in layers, each of the run-in layers consists of one of an a-C:H layer and an Me-C/a-C:H layer, the Me-C/a-C:H layer consisting essentially of Me′, C, and X′, the concentration of Me′ and C being given by the expression (Me′ a C 1-a′ ) 1-b X′ b , a′=0.25, Me′ consisting of the materials of Me, X′ consisting of the materials of X, a′ being the atomic fraction of Me′ if only Me′ and C are considered for a balance of elements in the Me-C/a-C:H layer; and
any combination thereof.
12. The sliding component according to claim 11 , wherein Me consists of chromium and X consists of hydrogen.
13. The sliding component according to claim 11 , wherein Me is chromium and X is a mixture of hydrogen and silicon.
14. The sliding component according to claim 11 , wherein a is about 0.45.
15. The sliding component according to claim 14 , wherein Me is chromium and X is hydrogen.
16. The sliding component according to claim 1 , wherein the sliding component consists of a piston ring.
17. A tribological system comprising the sliding component according to claim 1 .
18. The sliding component according to claim 1 , wherein a=0.45.