IP Library Granted Patent US 9,537,174
Granted Patent B2
US 9,537,174 · App. 13/389,129 · Granted Jan 3, 2017

Sulfide solid electrolyte

Inventors: Masahiro Tatsumisago (Sakai, JP); Akitoshi Hayashi (Sakai, JP); Shigenori Hama (Susono, JP); Koji Kawamoto (Susono, JP); Takamasa Ohtomo (Susono, JP)
Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
H01M10/0562H01M10/0525H01M2300/0071Y02E60/122Y02P70/54
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Quick Facts
Patent No.
US 9,537,174
App. No.
13/389,129
Granted
Jan 3, 2017
Kind
B2
Abstract

A sulfide solid electrolyte with excellent ion conductivity and a method for producing a crystallized glass contained in the sulfide solid electrolyte. A sulfide solid electrolyte comprising a crystallized glass represented by the following chemical formula yLi 2 S•(100-x-y)P 2 S 5 •xP 2 O 5 , wherein 0<x<25 and 67<y<80.

Claims (22)

1. A sulfide solid electrolyte comprising a crystallized glass represented by the following chemical formula (1):

75Li 2 S•(25- x )P 2 S 5 •x P 2 O 5   (1)

wherein:

0<x<25.

2. The sulfide solid electrolyte according to claim 1 , wherein the crystallized glass has a crystallinity of 50 to 100%.

3. The sulfide solid electrolyte according to claim 1 , having an ortho composition.

4. The sulfide solid electrolyte according to claim 1 , wherein the crystallized glass does not comprise a P 2 S 7 4− ion.

5. The sulfide solid electrolyte according to claim 1 , wherein 0<x≦20.

6. The sulfide solid electrolyte according to claim 1 , wherein 0<x≦15.

7. The sulfide solid electrolyte according to claim 1 , wherein 5≦x≦20.

8. The sulfide solid electrolyte according to claim 1 , wherein 5≦x≦15.

9. A method for producing a crystallized glass, comprising:

preparing a raw material composition comprising Li 2 S, P 2 S 5 and P 2 O 5 so that a content of Li 2 S is 75 mol % when a total content of Li 2 S, P 2 S 5 and P 2 O 5 is 100 mol %;

amorphizing the raw material composition; and

crystallizing a glass obtained by the amorphization by heating;

wherein the crystallized glass comprises a PS 4 3− ion but does not comprise a P 2 S 7 4− ion.

10. The method according to claim 9 , wherein the raw material composition is amorphized by mechanical milling.

11. A method for producing a crystallized glass, comprising:

preparing a raw material composition comprising Li 2 S, P 2 S 5 and P 2 O 5 so that a content of Li 2 S is 75 mol % when a total content of Li 2 S, P 2 S 5 and P 2 O 5 is 100 mol %;

amorphizing the raw material composition; and

crystallizing a glass obtained by the amorphization by heating.

12. The method according to claim 11 , wherein the raw material composition is amorphized by mechanical milling.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 23, 2012
From: TATSUMISAGO, MASAHIRO; HAYASHI, AKITOSHI; HAMA, SHIGENORI; KAWAMOTO, KOJI; OHTOMO, TAKAMASA
To: TOYOTA JIDOSHA KABUSHIKI KAISHA
Reel/Frame 027932/0023 →
Priority Claims (1)
JP 2009-208227 · Sep 9, 2009 · national
Continuity (1)
Related Publication 20120189918A1 · Jul 26, 2012