Sulfide solid electrolyte
A sulfide solid electrolyte with excellent ion conductivity and a method for producing a crystallized glass contained in the sulfide solid electrolyte. A sulfide solid electrolyte comprising a crystallized glass represented by the following chemical formula yLi 2 S•(100-x-y)P 2 S 5 •xP 2 O 5 , wherein 0<x<25 and 67<y<80.
1. A sulfide solid electrolyte comprising a crystallized glass represented by the following chemical formula (1):
75Li 2 S•(25- x )P 2 S 5 •x P 2 O 5 (1)
wherein:
0<x<25.
2. The sulfide solid electrolyte according to claim 1 , wherein the crystallized glass has a crystallinity of 50 to 100%.
3. The sulfide solid electrolyte according to claim 1 , having an ortho composition.
4. The sulfide solid electrolyte according to claim 1 , wherein the crystallized glass does not comprise a P 2 S 7 4− ion.
5. The sulfide solid electrolyte according to claim 1 , wherein 0<x≦20.
6. The sulfide solid electrolyte according to claim 1 , wherein 0<x≦15.
7. The sulfide solid electrolyte according to claim 1 , wherein 5≦x≦20.
8. The sulfide solid electrolyte according to claim 1 , wherein 5≦x≦15.
9. A method for producing a crystallized glass, comprising:
preparing a raw material composition comprising Li 2 S, P 2 S 5 and P 2 O 5 so that a content of Li 2 S is 75 mol % when a total content of Li 2 S, P 2 S 5 and P 2 O 5 is 100 mol %;
amorphizing the raw material composition; and
crystallizing a glass obtained by the amorphization by heating;
wherein the crystallized glass comprises a PS 4 3− ion but does not comprise a P 2 S 7 4− ion.
10. The method according to claim 9 , wherein the raw material composition is amorphized by mechanical milling.
11. A method for producing a crystallized glass, comprising:
preparing a raw material composition comprising Li 2 S, P 2 S 5 and P 2 O 5 so that a content of Li 2 S is 75 mol % when a total content of Li 2 S, P 2 S 5 and P 2 O 5 is 100 mol %;
amorphizing the raw material composition; and
crystallizing a glass obtained by the amorphization by heating.
12. The method according to claim 11 , wherein the raw material composition is amorphized by mechanical milling.