Preparation of polyolefin
Catalyst systems and methods for making and using the same are provided. The catalyst systems can include a plurality of silica particles and a metallocene catalyst and an activator supported on the plurality of silica particles. The polymerization catalysts have a particle size distribution in which about 10% of the particles have a size less than about 17 to about 23 micrometers, about 50% of the particles have a size less than about 40 to about 45 micrometers, and about 90% of the particles have a size less than about 72 to about 77 micrometers.
1. A method for forming resin particles, comprising:
forming a catalyst compound comprising hafnium;
mixing the catalyst compound with an activator to form a catalyst complex; and
combining the catalyst complex with a silica support to form a supported polymerization catalyst, wherein the supported polymerization catalyst has a productivity of at least about 7000 g polymer per g catalyst;
reacting the supported polymerization catalyst with at least ethylene in a polymerization reactor to form resin particles, wherein the resin particles have:
an average polymer particle size of at least about 0.660 mm;
a size distribution of at least about 20% greater than 1 mm in diameter; and
a ratio of fluidized bulk density to settled bulk density (FBD/SBD) of at least about 0.570.
2. The method of claim 1 , wherein forming the supported polymerization catalyst includes
mixing bis(n-propylcyclopentadienyl) hafnium (CH 3 ) 2 with methylaluminoxane to form the catalyst complex; and
drying the supported catalyst to bind the catalyst complex to the silica support.
3. The method of claim 1 , further comprising adding a comonomer to the polymerization reactor to control density of the resin particles.
4. The method of claim 1 , wherein the resin particles comprise a polymer having about a 0.7 dg/min MI, about a 0.912 g/cm 3 density, and about a 26 MFR at a temperature of the polymerization reactor of at least about 77° C.
5. The method of claim 1 , wherein the resin particles comprise a polymer having about a 1 dg/min MI, about a 0.918 g/cm 3 density, and about a 28 MFR at a temperature of the polymerization reactor of at least about 75° C.
6. The method of claim 1 , further comprising adding hydrogen to the fluidized bed reactor to control a melt index of the resin particles.
7. The method of claim 1 , wherein the polymerization reactor is a fluidized bed gas phase reactor.
8. The method of claim 1 , further comprising:
measuring a sample of the resin particles to obtain an initial product property; and
changing a process parameter to obtain a second product property, based, at least in part, on the initial product property.
9. The method of claim 8 , wherein measuring a sample comprises determining a physical property of a plastic sample.
10. The method of claim 8 , wherein measuring a sample comprises determining a physical property of a plastic sample.
11. The method of claim 3 , comprising adjusting a ratio of the comonomer to ethylene within the polymerization reactor to control at least one of the composition distribution, the molecular weight distribution, and the melt index (I 2 ) of a polyethylene.
12. The method of claim 6 , comprising adjusting a ratio of the hydrogen to ethylene within the polymerization reactor to control at least one of the composition distribution, the molecular weight distribution, and the melt index (I 2 ) of a polyethylene.