Undivided electrolytic cell and use thereof
The present invention relates to a method for producing an ammonium peroxodisulphate or an alkali-metal peroxodisulphate, to an undivided electrolytic cell constructed from individual components and to an electrolytic apparatus constructed from a plurality of electrolytic cells of this type.
1. An electrolysis cell, comprising:
(a) at least one tubular cathode;
(b) at least one rod-shaped or tubular anode, which comprises a conductive support coated with a conductive diamond layer;
(c) at least one inlet tube;
(d) at least one outlet tube; and,
(e) at least two distributing devices, wherein the distributing devices comprise at least one connector for one outlet or inlet tube and one connector for the anode, wherein the distributing devices connect the anode to a current source and the connector for the anode forms a hollow cylinder having radial holes distributed over the periphery of the hollow cylinder.
2. The electrolysis cell of claim 1 , wherein the electrolysis cell comprises a common electrolytic space without a diaphragm.
3. The electrolysis cell of claim 1 , wherein the spacing between the anode outer surface and the cathode inner surface is between 1 and 20 mm.
4. The electrolysis cell of claim 1 , wherein the internal diameter of the cathode is between 10 and 400 mm.
5. The electrolysis cell of claim 1 , wherein the anode and the cathode, each independently of one another, are between 20 and 120 cm long.
6. The electrolysis cell of claim 1 , wherein the conductive support is selected from the group consisting of silicon, germanium, titanium, zirconium, niobium, tantalum, molybdenum, tungsten, carbides of these elements, and/or aluminium or combinations of these elements.
7. The electrolysis cell of claim 1 , wherein the diamond layer is doped with at least one trivalent or at least one pentavalent main group or B-group element.
8. The electrolysis cell of claim 1 , wherein the cathode is made from lead, carbon, tin, platinum, nickel, alloys of these elements, zirconium and/or iron alloys.
9. The electrolysis cell of claim 1 , wherein an electrolyte of the electrolysis cell is fed through the inlet tube.
10. The electrolysis cell of claim 1 , wherein an electrolysis product is removed via the outlet tube of the electrolysis cell.
11. The electrolysis cell of claim 1 , wherein the distributing device distributes the electrolyte into an electrolytic space.
12. The electrolysis cell of claim 1 , wherein the components of the electrolysis cell can be individually replaced.
13. The electrolysis cell of claim 1 , wherein the distributing device is permanently connected to the anode.
14. An electrolysis apparatus comprising at least two of the electrolysis cells of claim 1 , wherein the electrolyte flows through the electrolysis cells one after the other and the electrolysis cells are electrochemically connected in parallel.
15. The electrolysis cell of claim 1 , wherein the diamond layer is doped with boron and/or phosphorous.
16. The electrolysis cell of claim 1 , wherein the cathode is made from acid-resistant high-grade steel.
17. The electrolysis cell of claim 1 , wherein an electrolytic space is present as an annular gap between the anode and the cathode.