Light conversion film, and backlight unit and display device having the same
A light conversion film including a first barrier film, a light conversion layer disposed on the first barrier film, the light conversion layer including a matrix resin and red quantum dots that are dispersed into the matrix resin, and a second barrier film disposed on the light conversion layer. The light conversion film satisfies following Equation (1): 5≦(weight of quantum dot within light conversion layer/total weight of light conversion layer)×100×t≦50, where, t is a thickness of the light conversion layer.
1. A light conversion film comprising:
a first barrier film;
a light conversion layer disposed on the first barrier film, the light conversion layer comprising a matrix resin, red quantum dots dispersed into the matrix resin, microphases each including at least the red quantum dots, and a dispersing agent on a surface of the microphases; and
a second barrier film disposed on the light conversion layer,
wherein the light conversion film satisfies the following Equation (1):
5≦(weight of the red quantum dots within the light conversion layer/total weight of light conversion layer)×100×t≦50 Equation (1):,
where t is a thickness of the light conversion layer, and
wherein the light conversion layer has the thickness t of about 5 μm to about 100 μm.
2. The light conversion film according to claim 1 , wherein the light conversion film satisfies Equation (2):
0.05≦(weight of the red quantum dots within the light conversion layer/total weight of light conversion layer)×100≦5 Equation (2):.
3. The light conversion film according to claim 1 , wherein, when excitation light having a wavelength of about 420 nm is irradiated, the light conversion film has emission peaks in a wavelength band of about 400 nm to about 450 nm and a wavelength band of about 600 nm to about 680 nm.
4. The light conversion film according to claim 1 , wherein the microphases include a quantum dot-polymer bead composite or quantum dot-oligomer liquid drop.
5. The light conversion film according to claim 4 , wherein the quantum dot-polymer bead composite further includes:
a polymer of which a portion of a chain is bonded to surfaces of the red quantum dots, the polymer comprising a polar group on a main or side chain thereof.
6. The light conversion film according to claim 4 , wherein the quantum dot-oligomer liquid drop further includes:
oligomer having polar moiety and nonpolar moiety, and
a nonpolar (meth) acrylate monomer.
7. The light conversion film according to claim 1 , wherein the light conversion layer further comprises a light scattering agent.
8. The light conversion film according to claim 7 , wherein the light scattering agent has a content of about 0.1 wt % to about 40 wt % of the total weight of the light conversion layer.
9. The light conversion film according to claim 7 , wherein the light scattering agent comprises a micro scattering agent having a diameter of about 0.5 μm to about 10 μm, a nano scattering agent having a diameter of about 5 nm to about 200 nm, and a combination thereof.
10. The light conversion film according to claim 9 , wherein the micro scattering agent has a content of about 1 wt % to about 40 wt % of the total weight of the light conversion layer.
11. The light conversion film according to claim 9 , wherein the nano scattering agent has a content of about 1 wt % to about 20 wt % of the total weight of the light conversion layer.
12. The light conversion film according to claim 1 , wherein the light conversion layer further comprises a photo-initiator.
13. The light conversion film according to claim 12 , wherein the photo-initiator has a content of about 1 wt % to about 15 wt % of the total weight of the light conversion layer.
14. The light conversion film according to claim 1 , wherein the light conversion layer further comprises a green phosphor.
15. The light conversion film according to claim 14 , wherein when excitation light having a wavelength of about 420 nm is irradiated, the light conversion film has emission peaks in a wavelength band of about 400 nm to about 450 nm, a wavelength band of about 500 nm to about 550 nm, and a wavelength band of about 600 nm to about 680 nm.
16. The light conversion film according to claim 1 , wherein each of the first and second barrier films has a moisture-permeation rate of about 10 −1 g/m 2 /day to about 10 −5 g/m 2 /day under a temperature of about 37.8° C. and relative humidity of about 100%.
17. The light conversion film according to claim 1 , wherein each of the first and second barrier films has a moisture-permeation rate of about 10 −1 cc/m 2 /day to about 10 −2 cc/m 2 /day under a temperature of about 23° C. and relative humidity of about 0%.
18. The light conversion film according to claim 1 , wherein each of the first and second barrier films has a thickness of about 20 μm to about 100 μm.
19. The light conversion film according to claim 2 , wherein the light conversion film has a light conversion efficiency of about 40% to about 80% that are expressed as following Equation (3):
light conversion efficiency={amount of red light emitted from light conversion film/total amount of light absorbed into light conversion film}×100 Equation (3):.
20. The light conversion film according to claim 1 , wherein after the light conversion film is disposed on a light emitting diode package comprising a green phosphor and a blue light emitting diode, a coordinate value measured by using a CIE coordinate system has an x value of about 0.255 to about 0.355.
21. The light conversion film according to claim 1 , wherein, after the light conversion film is disposed on a light emitting diode package comprising a green phosphor and a blue light emitting diode, a coordinate value measured by using a CIE coordinate system has a y value of about 0.255 to about 0.355.
22. A backlight unit comprising:
a light source unit comprising at least one light source; and
a light conversion film disposed on the light source unit,
wherein the light conversion film comprises:
a first barrier film;
a light conversion layer disposed on the first barrier film, the light conversion layer comprising a matrix resin, red quantum dots dispersed into the matrix resin, microphases each including at least the red quantum dots, and a dispersing agent on a surface of the microphases; and
a second barrier film disposed on the light conversion layer,
wherein the light conversion film satisfies following Equation (1):
5≦(weight of the red quantum dots within the light conversion layer/total weight of light conversion layer)×100×t≦50 Equation (1):,
where t is a thickness of the light conversion layer, and
wherein the light conversion layer has the thickness t of about 5 μm to about 100 μm.
23. The backlight unit according to claim 22 , wherein the at least one light source comprises a blue light source and a green light source.
24. The backlight unit according to claim 22 , wherein the light source comprises a light emitting diode package comprising a green phosphor and a blue light emitting diode.
25. The backlight unit according to claim 22 , wherein the light source comprises a blue light source, and
wherein the light conversion film further comprises a green phosphor in the light conversion layer.
26. A display device comprising:
a display panel; and
a backlight unit disposed under the display panel,
wherein the backlight unit comprises:
a light source unit comprising at least one light source; and
a light conversion film disposed on the light source unit,
wherein the light conversion film comprises:
a first barrier film;
a light conversion layer disposed on the first barrier film, the light conversion layer comprising a matrix resin, red quantum dots dispersed into the matrix resin, microphases each including at least the red quantum dots, and a dispersing agent on a surface of the microphases; and
a second barrier film disposed on the light conversion layer,
wherein the light conversion film satisfies following Equation (1):
5≦(weight of the red quantum dots within the light conversion layer/total weight of light conversion layer)×100×t≦50 Equation (1):,
where t is a thickness of the light conversion layer, and
wherein the light conversion layer has the thickness t of abut 5 μm to about 100 μm.
27. The display device according to claim 26 , wherein in the display device, a coordinate value measured by using a CIE coordinate system has an x value of about 0.255 to about 0.355.
28. The display device according to claim 26 , wherein in the display device, a coordinate value measured by using a CIE coordinate system has a y value of about 0.255 to about 0.355.