Method of producing solid state lithium battery module
The invention provides a method of producing a solid state lithium battery module in which the occurrence of short circuit caused by dendrites is suppressed. The invention solves this problem by providing a method of producing a solid state lithium battery module, including steps of: a pressing step of pressing a sulfide glass having an ion conductor containing a Li element, a P element, and a S element, and forming a solid electrolyte layer; and a restraining step of restraining a solid state lithium battery including the solid electrolyte layer, using restraining member, wherein, in the pressing step, the solid electrolyte layer is formed such that the average pore radius obtained by a mercury intrusion method is R (μm), and in the restraining step, the solid state lithium battery is restrained such that when the confining pressure is designated as P(MPa), the relationship: P≦−5900R+74 is satisfied.
1. A method of producing a solid state lithium battery module, the solid state lithium battery module comprising: a solid state lithium battery including a cathode active material layer containing a cathode active material, an anode active material layer containing an anode active material, and a solid electrolyte layer formed between the cathode active material layer and the anode active material layer; and a restraining member to apply a confining pressure in a thickness direction to the solid state lithium battery,
the method of producing the solid state lithium battery module comprising:
pressing a sulfide glass comprising LiI and an ion conductor containing a Li element, a P element, and a S element, and forming the solid electrolyte layer; and
restraining the solid state lithium battery including the solid electrolyte layer; using the restraining member such that the relationship: P≦−5900R+74 is satisfied,
wherein:
R represents an average pore radius in micrometers (μm) of the solid electrolyte layer formed by the pressing, the average pore radius being obtained by a mercury intrusion method,
P represents the confining pressure in megapascals (MPa) that is applied to the solid state lithium battery by the restraining member,
the ion conductor has a PS 4 3− structure, and a proportion of the PS 4 3− structure with respect to an overall anion structure of the ion conductor is 50 mol % or more, and
a proportion of LiI in the sulfide glass is in a range of from 20 mol % to 30 mol %.
2. The method of producing a solid state lithium battery module according to claim 1 , wherein the solid state lithium battery is restrained such that the relationship: −6400R+47≦P is satisfied.
3. A method of producing a solid state lithium battery module, the solid state lithium battery module comprising: a solid state lithium battery including a cathode active material layer containing a cathode active material, an anode active material layer containing an anode active material, and a solid electrolyte layer formed between the cathode active material layer and the anode active material layer; and a restraining member to apply a confining pressure in a thickness direction to the solid state lithium battery,
the method of producing the solid state lithium battery module comprising:
pressing a sulfide glass comprising LiI and an ion conductor containing a Li element, a P element, and a S element, and forming the solid electrolyte layer; and
restraining the solid state lithium battery including the solid electrolyte layer using the restraining member such that the relationship P≦8.9F−790 is satisfied,
wherein:
F represents a filling percentage (%) of the solid electrolyte layer formed by the pressing,
P represents the confining pressure in megapascals (MPa) that is applied to the solid state lithium battery by the restraining member,
the ion conductor has a PS 4 3− structure, and a proportion of the PS 4 3− structure with respect to an overall anion structure of the ion conductor is 50 mol % or more, and
a proportion of Lit in the sulfide glass is in a range of from 20 mol % to 30 mol %.
4. The method of producing a solid state lithium battery module according to claim 3 , wherein the solid state lithium battery is restrained such that the relationship: 7.4F−680≦P is satisfied.