Lithium-ion secondary battery and method for producing the same
A lithium-ion secondary battery of the present invention comprises a positive electrode including a positive electrode active material composite formed by compositing a lithium silicate-based material and a carbon material, a negative electrode including a negative electrode active material containing a silicon, and an electrolyte. The lithium-ion secondary battery satisfies 0.8<B/A<1.2, where A is irreversible capacity of the positive electrode and B is irreversible capacity of the negative electrode.
1. A lithium-ion secondary battery, comprising a positive electrode including a positive electrode active material composite formed by compositing a lithium silicate-based material and a carbon material, a negative electrode including a negative electrode active material containing a silicon, and an electrolyte, and
satisfying 0.8<B/A<1.2, where A is irreversible capacity of the positive electrode and B is irreversible capacity of the negative electrode.
2. The lithium-ion secondary battery according to claim 1 , satisfying 0.8<D/C<1.2, where C is reversible capacity of the positive electrode and D is reversible capacity of the negative electrode.
3. The lithium-ion secondary battery according to claim 1 , wherein the positive electrode active material composite is formed by compositing the lithium silicate-based material and the carbon material by mechanical milling of the lithium silicate-based material and the carbon material.
4. The lithium-ion secondary battery according to claim 3 , wherein the irreversible capacity of the positive electrode is adjusted by controlling at least one of milling speed and milling time of the mechanical milling.
5. The lithium-ion secondary battery according to claim 1 , wherein the lithium silicate-based material is expressed by a compositional formula Li 2+a−b A b M 1−β M′ β Si 1+α O 4+c , where A is at least one element selected from the group consisting of Na, K, Rb, and Cs, M is at least one element selected from the group consisting of Fe and Mn, and M′ is at least one element selected from the group consisting of Mg, Ca, Co, Al, Ni, Nb, Ti, Cr, Cu, Zn, Zr, V, Mo and W, and the subscripts are as follows: 0≦α≦0.2, 0≦β≦0.5, 0≦a<1, 0≦b<0.2, 0<c<0.3.
6. The lithium-ion secondary battery according to claim 1 , wherein the amount of the carbon material contained in the positive electrode active material composite is not less than 1% by mass and not more than 50% by mass of the total mass of the positive electrode active material composite.
7. The lithium-ion secondary battery according to claim 1 , wherein
the negative electrode active material comprises at least one of Si and SiO x , and
the SiO x has an overall composition expressed by a formula: SiO x (0.5≦x≦1.5) and comprises Si phase and SiO 2 phase.
8. The lithium-ion secondary battery according to claim 1 , wherein the negative electrode active material is synthesized from Si powder and the lithium silicate-based material of the positive electrode active material has an average particle size of not less than 10 nm and not more than 10 μm, and the carbon material of the positive electrode active material has an average particle size of not less than 10 nm and not more than 1 μm.
9. The lithium-ion secondary battery according to claim 1 , wherein the negative electrode active material is synthesized from SiO x powder and the lithium silicate-based material of the positive electrode active material has an average particle size of not less than 10 nm and not more than 20 μm, and the carbon material of the positive electrode active material has an average particle size of not less than 10 nm and not more than 1 μm.
10. A method for producing a lithium-ion secondary battery having a positive electrode including a positive electrode active material composite formed of compositing a lithium silicate-based material and a carbon material, a negative electrode including a negative electrode active material containing a silicon, and an electrolyte;
forming the positive electrode active material composite by compositing the lithium silicate-based material and the carbon material by mechanical milling of the lithium silicate-based material and the carbon material; and satisfying 0.8<B/A<1.2, where A is irreversible capacity of the positive electrode and B is irreversible capacity of the negative electrode.
11. The method for producing a lithium-ion secondary battery according to claim 10 , wherein the irreversible capacity of the positive electrode is adjusted by controlling at least one of milling speed and milling time of the mechanical milling.