Glass compositions and fibers made therefrom
Embodiments of the present invention provides fiberizable glass compositions formed from batch compositions comprising amounts of one or more glassy minerals, including perlite and/or pumice.
1. A fiberizable glass composition formed from a glass batch composition comprising at least 50 weight percent of a glassy mineral, wherein the glassy mineral comprises a combination of SiO 2 and Al 2 O 3 in an amount of at least 80 weight percent, and at least 5 weight percent of a sodium source, wherein the glass composition comprises 53-61 weight percent SiO 2 , from 8 to less than 12 weight percent Al 2 O 3 , less than 1 weight percent of Fe 2 O 3 , 0 weight percent B 2 O 3 , from greater than 14 to 18 weight percent alkali metal oxide component (R 2 O), 0-3 weight percent La 2 O 3 , and at least one metal oxide (RO) component selected from the group consisting of MgO, CaO, SrO, BaO, and ZnO, wherein CaO is present in an amount ranging from 7 to 26 weight percent of the glass composition, and optional ZnO in an amount ranging from 0 to 3 weight percent of the glass composition, and wherein R 2 O comprises K 2 O in an amount ranging from 2 to 4 weight percent.
2. The fiberizable glass composition of claim 1 , wherein the glass batch composition comprises at least 10 weight percent of a source of both silicon and aluminum.
3. The fiberizable glass composition of claim 1 , wherein the glass batch composition comprises at least 10 weight percent of a source of silicon.
4. The fiberizable glass composition of claim 1 , wherein the glass batch composition comprises at least 10 weight percent of a source of aluminum.
5. The fiberizable glass composition of claim 1 , wherein the glass batch composition comprises at least 10 weight percent of the sodium source.
6. The fiberizable glass composition of claim 1 , wherein the glassy mineral comprises perlite, pumice or mixtures thereof.
7. A fiberizable glass composition, comprising:
53-61 weight percent SiO 2 ;
from 8 to less than 12 weight percent Al 2 O 3 ;
from greater than 14 to 18 weight percent alkali metal oxide component (R 2 O);
0-3 weight percent La 2 O 3 ; and
at least one metal oxide (RO) component selected from the group consisting of MgO, CaO, SrO, BaO, and ZnO,
wherein the metal oxide component is present in an amount to provide a ratio R 2 O/RO ranging from about 0.34 to about 1.5, wherein CaO is present in an amount ranging from 7 to 26 weight percent of the glass composition and optional ZnO in an amount ranging from 0 to 3 weight percent of the glass composition, wherein R 2 O comprises K 2 O in an amount ranging from 2 to 4 weight percent, and wherein the glass composition comprises less than 1 weight percent of Fe 2 O 3 and 0 weight percent B 2 O 3 .
8. A glass fiber formed from the glass composition of claim 7 .
9. The glass composition of claim 7 , wherein the RO component is present in an amount ranging from 7 weight percent to 30.5 weight percent.
10. The glass composition of claim 7 , wherein MgO is present.
11. The glass composition of claim 7 , wherein MgO is present in an amount up to 5 weight percent.
12. The glass composition of claim 7 , wherein R 2 O comprises Na 2 O in an amount ranging from 6.5 to 16 weight percent.
13. The glass composition of claim 7 , wherein the glass composition has a fiber forming temperature ranging from about 1120° C. to about 1300° C.
14. The glass composition of claim 7 , wherein the difference between forming temperature and liquidus temperature of the glass composition is at least about 65° C.
15. The glass composition of claim 7 , wherein the difference between forming temperature and liquidus temperature of the glass composition ranges from about 45° C. to about 165° C.
16. The glass composition of claim 7 , further comprising from greater than 0 to 2 Li 2 O.
17. The glass composition of claim 7 , further comprising from greater than 0 to 3 TiO 2 .
18. The glass composition of claim 7 , further comprising from greater than 0 to 3 MnO 2 .
19. A fiberizable glass composition formed from a glass batch composition comprising at least 50 weight percent of a glassy mineral, wherein the glassy mineral comprises a combination of SiO 2 and Al 2 O 3 in an amount of at least 80 weight percent, and at least 5 weight percent of a sodium source, wherein the glass composition comprises from greater than 11 to 14 weight percent Al 2 O 3 , less than 1 weight percent of Fe 2 O 3 , 0 weight percent B 2 O 3 , from greater than 10 to 18 weight percent alkali metal oxide component (R 2 O), and at least one metal oxide (RO) component selected from the group consisting of MgO, CaO, SrO, BaO, and ZnO, wherein CaO is present in an amount ranging from 7 to 26 weight percent of the glass composition, wherein R 2 O comprises Na 2 O in an amount greater than 10 weight percent and Li 2 O in an amount from greater than 0 to 2 weight percent, and wherein optional ZnO is in an amount ranging from 0 to 3 weight percent of the glass composition.
20. A fiberizable glass composition, comprising:
from greater than 60 to 64 weight percent SiO 2 ;
from greater than 11 to 14 weight percent Al 2 O 3 ;
from greater than 10 to 18 weight percent alkali metal oxide component (R 2 O); and
at least one metal oxide (RO) component selected from the group consisting of MgO, CaO, SrO, BaO, and ZnO,
wherein the metal oxide component is present in an amount to provide a ratio of R 2 O/RO ranging from about 0.34 to about 1.5, wherein CaO is present in an amount ranging from 7 to 26 weight percent of the glass composition and optional ZnO in an amount ranging from 0 to 3 weight percent of the glass composition, wherein R 2 O comprises Na 2 O in an amount greater than 10 weight percent and K 2 O in an amount greater than 0 weight percent, and wherein the glass composition comprises less than 1 weight percent of Fe 2 O 3 and 0 weight percent B 2 O 3 .