IP Library › Granted Patent US 9,608,123
Granted Patent B2
US 9,608,123 · App. 14/609,814 · Granted Mar 28, 2017

Method for manufacturing semiconductor device

Inventors: Yuji Egi (Isehara, JP); Hideomi Suzawa (Atsugi, JP); Shinya Sasagawa (Atsugi, JP)
Assignee: Semiconductor Energy Laboratory Co., Ltd.
H01L29/7869H01L27/127H01L27/14616H01L29/0684H01L29/78603H01L29/78693H01L21/02565H01L27/1225
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Quick Facts
Patent No.
US 9,608,123
App. No.
14/609,814
Granted
Mar 28, 2017
Kind
B2
Abstract

In a semiconductor device including a transistor in which an oxide semiconductor layer, a gate insulating layer, and a gate electrode layer on side surfaces of which sidewall insulating layers are provided are stacked in this order, a source electrode layer and a drain electrode layer are provided in contact with the oxide semiconductor layer and the sidewall insulating layers. In a process for manufacturing the semiconductor device, a conductive layer and an interlayer insulating layer are stacked to cover the oxide semiconductor layer, the sidewall insulating layers, and the gate electrode layer. Then, parts of the interlayer insulating layer and the conductive layer over the gate electrode layer are removed by a chemical mechanical polishing method, so that a source electrode layer and a drain electrode layer are formed. Before formation of the gate insulating layer, cleaning treatment is performed on the oxide semiconductor layer.

Claims (107)

1. A semiconductor device comprising:

an island-shaped oxide semiconductor layer over an oxide insulating layer including an insulating surface;

a source electrode layer and a drain electrode layer over the island-shaped oxide semiconductor layer;

a gate insulating layer over the island-shaped oxide semiconductor layer;

a gate electrode layer over the gate insulating layer;

an insulating layer over the gate electrode layer, the insulating layer overlapping the gate electrode layer;

a sidewall insulating layer over the gate insulating layer, the sidewall insulating layer covering a side surface of the gate electrode layer and a side surface of the insulating layer;

a conductive layer over the island-shaped oxide semiconductor layer, the gate insulating layer, the gate electrode layer, the insulating layer, and the sidewall insulating layer; and

an interlayer insulating layer over the source electrode layer and the drain electrode layer,

wherein a source region of the island-shaped oxide semiconductor layer includes a dopant,

wherein the island-shaped oxide semiconductor layer includes a region in a vicinity of a top surface of the island-shaped oxide semiconductor layer,

wherein a concentration of chlorine in the region is lower than or equal to 3.4×10 17 atoms/cm 3 when being measured by secondary ion mass spectrometry,

wherein a concentration of boron in the region is lower than or equal to 4.5×10 18 atoms/cm 3 when being measured by secondary ion mass spectrometry,

wherein a concentration of aluminum in the region is lower than or equal to 7.5×10 17 atoms/cm 3 when being measured by secondary ion mass spectrometry, and

wherein a concentration of fluorine in the region is lower than or equal to 8.9×10 18 atoms/cm 3 when being measured by secondary ion mass spectrometry.

2. The semiconductor device according to claim 1 , wherein the oxide insulating layer contains excessive oxygen.

3. The semiconductor device according to claim 1 , wherein the oxide insulating layer is a silicon oxide film.

4. The semiconductor device according to claim 1 ,

wherein the oxide insulating layer includes silicon oxide,

wherein the composition formula of the silicon oxide is SiO 2+α , and

wherein α>0.

5. The semiconductor device according to claim 1 , wherein the oxide insulating layer is capable of supplying oxygen to the island-shaped oxide semiconductor layer.

6. The semiconductor device according to claim 1 , further comprising a layer containing aluminum oxide over the interlayer insulating layer.

7. A semiconductor device comprising:

an island-shaped oxide semiconductor layer over an oxide insulating layer including an insulating surface;

a source electrode layer and a drain electrode layer over the island-shaped oxide semiconductor layer;

a gate insulating layer over the island-shaped oxide semiconductor layer;

a gate electrode layer over the gate insulating layer;

an insulating layer over the gate electrode layer, the insulating layer overlapping the gate electrode layer;

a sidewall insulating layer over the gate insulating layer, the sidewall insulating layer covering a side surface of the gate electrode layer and a side surface of the insulating layer;

a conductive layer over the island-shaped oxide semiconductor layer, the gate insulating layer, the gate electrode layer, the insulating layer, and the sidewall insulating layer; and

an interlayer insulating layer over the source electrode layer and the drain electrode layer,

wherein a source region of the island-shaped oxide semiconductor layer includes a dopant,

wherein the island-shaped oxide semiconductor layer includes a region in a vicinity of a top surface of the island-shaped oxide semiconductor layer,

wherein a concentration of chlorine in the region is lower than or equal to 3.3×10 17 atoms/cm 3 when being measured by secondary ion mass spectrometry,

wherein a concentration of boron in the region is lower than or equal to 1.2×10 18 atoms/cm 3 when being measured by secondary ion mass spectrometry,

wherein a concentration of aluminum in the region shows a noise level value when being measured by secondary ion mass spectrometry, and

wherein a concentration of fluorine in the region is lower than or equal to 7.2×10 18 atoms/cm 3 when being measured by secondary ion mass spectrometry.

8. The semiconductor device according to claim 7 , wherein the oxide insulating layer contains excessive oxygen.

9. The semiconductor device according to claim 7 , wherein the oxide insulating layer is a silicon oxide film.

10. The semiconductor device according to claim 7 ,

wherein the oxide insulating layer includes silicon oxide,

wherein the composition formula of the silicon oxide is SiO 2+α , and

wherein α>0.

11. The semiconductor device according to claim 7 , wherein the oxide insulating layer is capable of supplying oxygen to the island-shaped oxide semiconductor layer.

12. The semiconductor device according to claim 7 , further comprising a layer containing aluminum oxide over the interlayer insulating layer.

13. A semiconductor device comprising:

an island-shaped oxide semiconductor layer over an oxide insulating layer including an insulating surface;

a source electrode layer and a drain electrode layer over the island-shaped oxide semiconductor layer;

a gate insulating layer over the island-shaped oxide semiconductor layer;

a gate electrode layer over the gate insulating layer;

an insulating layer over the gate electrode layer, the insulating layer overlapping the gate electrode layer;

a sidewall insulating layer over the gate insulating layer, the sidewall insulating layer covering a side surface of the gate electrode layer and a side surface of the insulating layer;

a conductive layer over the island-shaped oxide semiconductor layer, the gate insulating layer, the gate electrode layer, the insulating layer, and the sidewall insulating layer; and

an interlayer insulating layer over the source electrode layer and the drain electrode layer,

wherein a source region of the island-shaped oxide semiconductor layer includes a dopant,

wherein the island-shaped oxide semiconductor layer includes a region in a vicinity of a top surface of the island-shaped oxide semiconductor layer,

wherein a concentration of chlorine in the region is lower than or equal to 1.8×10 18 atoms/cm 3 when being measured by secondary ion mass spectrometry,

wherein a concentration of boron in the region is lower than or equal to 1.6×10 19 atoms/cm 3 when being measured by secondary ion mass spectrometry,

wherein a concentration of aluminum in the region is lower than or equal to 8.8×10 17 atoms/cm 3 when being measured by secondary ion mass spectrometry, and

wherein a concentration of carbon in the region is lower than or equal to 2.3×10 20 atoms/cm 3 when being measured by secondary ion mass spectrometry.

14. The semiconductor device according to claim 13 , wherein the oxide insulating layer contains excessive oxygen.

15. The semiconductor device according to claim 13 , wherein the oxide insulating layer is a silicon oxide film.

16. The semiconductor device according to claim 13 ,

wherein the oxide insulating layer includes silicon oxide,

wherein the composition formula of the silicon oxide is SiO 2+α , and

wherein α>0.

17. The semiconductor device according to claim 13 , wherein the oxide insulating layer is capable of supplying oxygen to the island-shaped oxide semiconductor layer.

18. The semiconductor device according to claim 13 , further comprising a layer containing aluminum oxide over the interlayer insulating layer.

19. A semiconductor device comprising:

an island-shaped oxide semiconductor layer over an oxide insulating layer including an insulating surface;

a source electrode layer and a drain electrode layer over the island-shaped oxide semiconductor layer;

a gate insulating layer over the island-shaped oxide semiconductor layer;

a gate electrode layer over the gate insulating layer; and

an insulating layer over the gate electrode layer, the insulating layer overlapping the gate electrode layer,

wherein a source region of the island-shaped oxide semiconductor layer includes a dopant,

wherein the island-shaped oxide semiconductor layer includes a region in a vicinity of a top surface of the island-shaped oxide semiconductor layer,

wherein a concentration of chlorine in the region is lower than or equal to 3.4×10 17 atoms/cm 3 when being measured by secondary ion mass spectrometry,

wherein a concentration of boron in the region is lower than or equal to 4.5×10 18 atoms/cm 3 when being measured by secondary ion mass spectrometry,

wherein a concentration of aluminum in the region is lower than or equal to 7.5×10 17 atoms/cm 3 when being measured by secondary ion mass spectrometry, and

wherein a concentration of fluorine in the region is lower than or equal to 8.9×10 18 atoms/cm 3 when being measured by secondary ion mass spectrometry.

20. The semiconductor device according to claim 19 , wherein the oxide insulating layer is a silicon oxide film.

21. A semiconductor device comprising:

an island-shaped oxide semiconductor layer over an oxide insulating layer including an insulating surface;

a source electrode layer and a drain electrode layer over the island-shaped oxide semiconductor layer;

a gate insulating layer over the island-shaped oxide semiconductor layer;

a gate electrode layer over the gate insulating layer; and

an insulating layer over the gate electrode layer, the insulating layer overlapping the gate electrode layer,

wherein a source region of the island-shaped oxide semiconductor layer includes a dopant,

wherein the island-shaped oxide semiconductor layer includes a region in a vicinity of a top surface of the island-shaped oxide semiconductor layer, wherein a concentration of chlorine in the region is lower than or equal to 3.3×10 17 atoms/cm 3 when being measured by secondary ion mass spectrometry,

wherein a concentration of boron in the region is lower than or equal to 1.2×10 18 atoms/cm 3 when being measured by secondary ion mass spectrometry,

wherein a concentration of aluminum in the region shows a noise level value when being measured by secondary ion mass spectrometry, and

wherein a concentration of fluorine in the region is lower than or equal to 7.2×10 18 atoms/cm 3 when being measured by secondary ion mass spectrometry.

22. The semiconductor device according to claim 21 , wherein the oxide insulating layer is a silicon oxide film.

23. A semiconductor device comprising:

an island-shaped oxide semiconductor layer over an oxide insulating layer including an insulating surface;

a source electrode layer and a drain electrode layer over the island-shaped oxide semiconductor layer;

a gate insulating layer over the island-shaped oxide semiconductor layer;

a gate electrode layer over the gate insulating layer; and

an insulating layer over the gate electrode layer, the insulating layer overlapping the gate electrode layer,

wherein a source region of the island-shaped oxide semiconductor layer includes a dopant,

wherein the island-shaped oxide semiconductor layer includes a region in a vicinity of a top surface of the island-shaped oxide semiconductor layer,

wherein a concentration of chlorine in the region is lower than or equal to 1.8×10 18 atoms/cm 3 when being measured by secondary ion mass spectrometry,

wherein a concentration of boron in the region is lower than or equal to 1.6×10 19 atoms/cm 3 when being measured by secondary ion mass spectrometry,

wherein a concentration of aluminum in the region is lower than or equal to 8.8×10 17 atoms/cm 3 when being measured by secondary ion mass spectrometry, and

wherein a concentration of carbon in the region is lower than or equal to 2.3×10 20 atoms/cm 3 when being measured by secondary ion mass spectrometry.

24. The semiconductor device according to claim 23 , wherein the oxide insulating layer is a silicon oxide film.

Priority Claims (1)
JP 2011-263027 · Nov 30, 2011 · national
Continuity (2)
Continuation 13677663 · Nov 15, 2012
Related Publication 20150137124A1 · May 21, 2015