Organic electroluminescent element
An organic electroluminescence device includes a pair of electrodes and an organic compound layer interposed therebetween. The organic compound layer includes a plurality of emitting layers at least including a first emitting layer and a second emitting layer. The first emitting layer contains a first host material and a fluorescent first luminescent material. The second emitting layer contains a second luminescent material that is different from the first luminescent material. A difference ΔST(H1) between singlet energy EgS(H1) of the first host material and an energy gap Eg 77K (H1) at 77[K] of the first host material satisfies a specific relationship. One of the first luminescent material and the second luminescent material has a main peak wavelength from 400 nm to less than 500 nm and the other of the first luminescent material and the second luminescent material has a main peak wavelength from 500 nm to 700 nm.
1. An organic electroluminescence device comprising a pair of electrodes and an organic compound layer interposed between the pair of electrodes, wherein
the organic compound layer comprises a plurality of emitting layers at least comprising a first emitting layer and a second emitting layer,
the first emitting layer comprises a first host material and a fluorescent first luminescent material,
the second emitting layer comprises a second luminescent material that is different from the first luminescent material,
a difference ΔST(H1) between singlet energy EgS(H1) of the first host material and an energy gap Eg 77K (H1) at 77[K] of the first host material satisfies a formula (1) below,
Δ ST ( H 1)= EgS ( H 1)− Eg 77K ( H 1)<0.3 [eV] (1) and
the first luminescent material has a main peak wavelength from 400 nm to less than 500 nm and the second luminescent material has a main peak wavelength from 500 nm to 700 nm, or alternatively,
the first luminescent material has a main peak wavelength from 500 nm to 700 nm and the second luminescent material has a main peak wavelength from 400 nm to less than 500 nm.
2. The organic electroluminescence device according to claim 1 , wherein
the first emitting layer further comprises a second host material, and
the singlet energy EgS(H1) of the first host material, singlet energy EgS(H2) of the second host material, and singlet energy EgS(D) of the first luminescent material satisfy formulae (2) and (3) below,
EgS ( H 1)> EgS ( D ) (2)
EgS ( H 2)> EgS ( D ) (3).
3. The organic electroluminescence device according to claim 1 , wherein
the organic compound layer comprises a plurality of emitting units and an intermediate unit that is adjacent to the plurality of emitting units and connects the plurality of emitting units to each other, and
at least one emitting unit of the plurality of emitting units comprises the first emitting layer.
4. The organic electroluminescence device according to claim 3 , wherein
the plurality of emitting units at least comprises a first emitting unit and a second emitting unit,
the first emitting unit comprises the first emitting layer and the first luminescent material exhibits blue fluorescence,
the second emitting unit comprises the second emitting layer, and the second emitting layer comprises a phosphorescent material as the second luminescent material and a third host material.
5. The organic electroluminescence device according to claim 1 , wherein
an anode, the first emitting layer, the second emitting layer, and a cathode are laminated in this order.
6. The organic electroluminescence device according to claim 1 , wherein
the second emitting layer is laminated adjacent to the first emitting layer.
7. The organic electroluminescence device according to claim 1 , wherein
the energy gap Eg 77K (H1) at 77[K] of the first host material and the energy gap Eg 77k (D) at 77K of the first luminescent material satisfy a formula (7) below:
Δ T=Eg 77k ( H 1)− Eg 77K ( D )≧0.5[eV] (7).
8. The organic electroluminescence device according to claim 1 , wherein
the energy gap Eg 77K (H1) at 77[K] of the first host material and the energy gap Eg 77k (D) at 77K of the first luminescent material satisfy a formula (7-1) below:
Δ T=Eg 77k ( H 1)− Eg 77K ( D )≧0.9[eV] (7-1).
9. The organic electroluminescence device according to claim 1 , wherein
the energy gap Eg 77K (H1) at 77[K] of the first host material and the energy gap Eg 77k (D) at 77K of the first luminescent material satisfy a formula (7-2) below:
Δ T=Eg 77k ( H 1)− Eg 77K ( D )≧1.0[eV] (7-2).
10. The organic electroluminescence device according to claim 1 , wherein the second luminescent material is a phosphorescent material.
11. The organic electroluminescence device according to claim 1 , wherein the second emitting layer comprises the second luminescent material that is a phosphorescent material; and a third host material.