IP Library Granted Patent US 9,617,169
Granted Patent B2
US 9,617,169 · App. 14/992,244 · Granted Apr 11, 2017

Transiently-operated desalination systems with heat recovery and associated methods

Inventors: Prakash Narayan Govindan (Melrose, MA); Maximus G. St. John (Boston, MA); Steven Lam (Medford, MA); Mark Zaloudek (Waltham, MA); Karim M. Chehayeb (Beirut, LB); Samar Shah (Malden, MA)
Assignee: Gradiant Corporation
C02F1/10B01D3/16B01D3/346C02F1/5245C02F5/02C02F2001/5218C02F2101/12C02F2101/322C02F2101/325C02F2103/08C02F2301/046
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Quick Facts
Patent No.
US 9,617,169
App. No.
14/992,244
Granted
Apr 11, 2017
Kind
B2
Abstract

Systems and methods related to desalination systems are described herein. According to some embodiments, the desalination systems are transiently operated and/or configured to facilitate transient operation. In some embodiments, a liquid stream comprising water and at least one dissolved salt is circulated through a fluidic circuit comprising a desalination system. In some embodiments, a portion of the desalination system (e.g., a humidifier) is configured to remove at least a portion of the water from the liquid stream to produce a concentrated brine stream enriched in the dissolved salt. In certain cases, the concentrated brine stream is recirculated through the fluidic circuit until the concentrated brine stream reaches a relatively high density (e.g., at least about 10 pounds per gallon) and/or a relatively high salinity (e.g., a total dissolved salt concentration of at least about 25 wt %). In certain embodiments, additional salt is added to the concentrated brine stream to produce an ultra-high-density brine stream (e.g., a brine stream having a density of at least about 11.7 pounds per gallon). Some aspects relate to a system that is configured to promote energy efficiency by recovering heat from the recirculated concentrated brine stream upon discharge from the fluidic circuit.

Claims (43)

1. A method for producing a concentrated brine stream, comprising:

supplying a first liquid stream comprising water and a dissolved salt at an initial concentration to a fluidic circuit comprising a desalination system, wherein the desalination system removes at least a portion of the water from the first liquid stream to produce a first concentrated brine stream comprising water and the dissolved salt at a second concentration higher than the initial concentration of the first liquid stream;

recirculating the first concentrated brine stream through the fluidic circuit to remove at least a portion of the water from the first concentrated brine stream, forming a recirculated first concentrated brine stream comprising water and the dissolved salt at a third concentration higher than the second concentration of the first concentrated brine stream;

discharging the recirculated first concentrated brine stream from the fluidic circuit when the recirculated first concentrated brine stream reaches a density of at least about 10 pounds per gallon, wherein discharging the recirculated first concentrated brine stream comprises flowing the recirculated first concentrated brine stream through a first portion of a heat exchanger;

supplying a second liquid stream comprising water and a dissolved salt at an initial concentration to the fluidic circuit comprising the desalination system, wherein supplying the second liquid stream comprises flowing the second liquid stream through a second portion of the heat exchanger, wherein heat is transferred from the recirculated first concentrated brine stream to the second liquid stream in the heat exchanger, and wherein the desalination system removes at least a portion of the water from the second liquid stream to produce a second concentrated brine stream comprising water and the dissolved salt at a second concentration higher than the initial concentration of the second liquid stream;

recirculating the second concentrated brine stream through the fluidic circuit to remove at least a portion of the water from the second concentrated brine stream, forming a recirculated second concentrated brine stream comprising water and the dissolved salt at a third concentration higher than the second concentration of the second concentrated brine stream; and

discharging the recirculated second concentrated brine stream from the fluidic circuit when the recirculated second concentrated brine stream reaches a density of at least about 10 pounds per gallon.

2. The method according to claim 1 , wherein the recirculated first concentrated brine stream has a salinity of at least about 25% upon discharge from the fluidic circuit and/or the recirculated second concentrated brine stream has a salinity of at least about 25% upon discharge from the fluidic circuit.

3. The method according to claim 1 , further comprising pre-treating the first liquid stream and/or the second liquid stream to remove at least a portion of at least one scale-forming ion.

4. The method according to claim 1 , further comprising pre-treating the first liquid stream and/or the second liquid stream to remove at least a portion of a suspended and/or emulsified immiscible phase.

5. The method according to claim 1 , further comprising pre-treating the first liquid stream and/or the second liquid stream to remove at least a portion of suspended solids.

6. The method according to claim 1 , further comprising precipitating at least a portion of the salt from the first concentrated brine stream and/or the recirculated first concentrated brine stream; and/or precipitating at least a portion of the salt from the second concentrated brine stream and/or the recirculated second concentrated brine stream.

7. A method for producing a concentrated brine stream, comprising:

supplying a first liquid stream comprising water and a dissolved salt at an initial concentration to a feed tank;

flowing the first liquid stream from the feed tank to a fluidic circuit comprising a desalination system, wherein the desalination system removes at least a portion of the water from the first liquid stream to produce a first concentrated brine stream comprising water and the dissolved salt at a second concentration higher than the initial concentration of the first liquid stream;

recirculating the first concentrated brine stream through the fluidic circuit to remove at least a portion of the water from the first concentrated brine stream, forming a recirculated first concentrated brine stream comprising water and the dissolved salt at a third concentration higher than the second concentration of the first concentrated brine stream;

discharging the recirculated first concentrated brine stream from the fluidic circuit when the recirculated first concentrated brine stream reaches a density of at least about 10 pounds per gallon, wherein discharging the recirculated first concentrated brine stream comprises flowing the recirculated first concentrated brine stream through a first portion of a heat exchanger to a concentrated brine tank;

supplying a second liquid stream comprising water and a dissolved salt at an initial concentration to the feed tank, wherein supplying the second liquid stream comprises flowing the second liquid stream through a second portion of the heat exchanger, wherein heat is transferred from the recirculated first concentrated brine stream to the second liquid stream in the heat exchanger;

flowing the second liquid stream from the feed tank to the fluidic circuit comprising the desalination system, wherein the desalination system removes at least a portion of the water from the second liquid stream to produce a second concentrated brine stream comprising water and the dissolved salt at a second concentration higher than the initial concentration of the second liquid stream;

recirculating the second concentrated brine stream through the fluidic circuit to remove at least a portion of the water from the second concentrated brine stream, forming a recirculated second concentrated brine stream comprising water and the dissolved salt at a third concentration higher than the second concentration of the second concentrated brine stream;

discharging the recirculated second concentrated brine stream from the fluidic circuit when the recirculated second concentrated brine stream reaches a density of at least about 10 pounds per gallon, wherein discharging the recirculated second concentrated brine stream comprises flowing the recirculated second concentrated brine stream through the first portion of the heat exchanger to the concentrated brine tank; and

flowing a first volume of liquid from the concentrated brine tank to the first portion of the heat exchanger while flowing a second volume of liquid from the feed tank to the second portion of the heat exchanger, wherein heat is transferred from the first volume of liquid to the second volume of liquid.

8. The method according to claim 7 , wherein the recirculated first concentrated brine stream and/or recirculated second concentrated brine stream has a salinity of at least about 25% upon discharge from the fluidic circuit.

9. The method according to claim 7 , further comprising pre-treating the first liquid stream and/or the second liquid stream to remove at least a portion of at least one scale-forming ion.

10. The method according to claim 7 , further comprising pre-treating the first liquid stream and/or the second liquid stream to remove at least a portion of a suspended and/or emulsified immiscible phase and/or at least a portion of suspended solids.

11. The method according to claim 7 , further comprising precipitating at least a portion of the salt from the first concentrated brine stream and/or the recirculated first concentrated brine stream; and/or precipitating at least a portion of the salt from the second concentrated brine stream and/or the recirculated second concentrated brine stream.

12. The method according to claim 1 , wherein the desalination system comprises one or more desalination units.

13. The method according to claim 12 , wherein the one or more desalination units comprise a mechanical vapor compression unit, a multi-effect distillation unit, a multi-stage flash unit, and/or a vacuum distillation unit.

14. The method according to claim 12 , wherein the one or more desalination units comprise two or more desalination units.

15. The method according to claim 14 , wherein the two or more desalination units are the same or different types of desalination units.

16. The method according to claim 7 , wherein the desalination system comprises one or more desalination units.

17. The method according to claim 16 , wherein the one or more desalination units comprise a mechanical vapor compression unit, a multi-effect distillation unit, a multi-stage flash unit, and/or a vacuum distillation unit.

18. The method according to claim 16 , wherein the one or more desalination units comprise two or more desalination units.

19. The method according to claim 18 , wherein the two or more desalination units are the same or different types of desalination units.

20. A system for treating a liquid comprising water and a dissolved salt at a first concentration, comprising:

a bubble column humidifier, comprising:

a humidifier gas inlet in fluid communication with a source of a non-condensable gas;

a humidifier gas outlet;

a humidifier liquid inlet in fluid communication with a source of the liquid;

a humidifier liquid outlet; and

a first stage comprising a first bubble generator, a first liquid layer comprising at least a portion of the liquid, and a gas distribution region, wherein the humidifier gas inlet is in fluid communication with the first bubble generator,

wherein the bubble column humidifier removes at least a portion of the water from a stream of the liquid to produce a bubble column humidifier liquid outlet stream comprising water and the dissolved salt at a second concentration greater than the first concentration, wherein the bubble column humidifier liquid outlet stream exits the bubble column humidifier through the humidifier liquid outlet; and

a precipitator in fluid communication with the humidifier liquid outlet of the bubble column humidifier, wherein the precipitator precipitates at least a portion of the dissolved salt from bubble column humidifier liquid outlet stream.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 14, 2016
From: GOVINDAN, PRAKASH NARAYAN; ST. JOHN, MAXIMUS G.; LAM, STEVEN; ZALOUDEK, MARK; CHEHAYEB, KARIM M.; SHAH, SAMAR
To: GRADIANT CORPORATION
Reel/Frame 037485/0614 →
Continuity (2)
Continuation 14719189 · May 21, 2015
Related Publication 20160340208A1 · Nov 24, 2016