IP Library › Granted Patent US 9,624,322
Granted Patent B2
US 9,624,322 · App. 13/635,055 · Granted Apr 18, 2017

Method of producing water absorbent resin

Inventors: Sumio Okuda (Himeji, JP); Syuji Kanzaki (Himeji, JP); Kunihiko Ishizaki (Himeji, JP); Shinichi Fujino (Himeji, JP); Kozo Nogi (Himeji, JP)
Assignee: Nippon Shukubai Co., Ltd.
C08F120/06B07B1/54B07B1/56B07B13/16C08F6/008C08F220/06C08J3/24C08J3/245G01N15/0272B07B1/28C08J2300/14G01N2015/0277G01N2015/0288
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Quick Facts
Patent No.
US 9,624,322
App. No.
13/635,055
Granted
Apr 18, 2017
Kind
B2
Abstract

A method for producing a water absorbent resin, the method including a polymerization step, a drying step, a classification step, and a surface crosslinking step. The classification step carried out before or after the surface crosslinking step requires use of a tapping material and a metal sieve mesh, in which the tapping material being heated at 40° C. to 100° C. is installed below the metal sieve mesh, and the metal sieve mesh has an area of 1 to 10 m 2 /sheet. The classification step further requires introducing a classification aid particle, which has a specific gravity different from that of the water absorbent resin, to the metal sieve mesh; and monitoring the presence or absence of damage to the metal sieve mesh.

Claims (13)

1. A method for producing a water absorbent resin comprising:

a polymerization step of polymerizing an aqueous solution of acrylic acid (salt) to obtain a water-containing gel-like crosslinked polymer;

a drying step of drying the water-containing gel-like crosslinked polymer to obtain a water absorbent resin powder;

a classification step of classifying the water absorbent resin powder; and

a surface crosslinking step of surface crosslinking the water absorbent resin powder,

wherein in the classification step that is carried out before the surface crosslinking step, a tapping material being heated at 40° C. to 100° C. is installed below a metal sieve mesh used in the classification step, the area of the metal sieve mesh being 1 to 10 [m 2 /sheet]; and the dew point of the atmosphere in which the classification step is carried out is −5° C. or higher and 15° C. or lower.

2. The method according to claim 1 , wherein the tapping material is installed on a punching metal that is provided into plural compartments.

3. The method according to claim 1 , wherein the material of the metal sieve mesh is SUS304 or SUS316, and the surface roughness (Rz) of the inner surface of the metal sieve mesh is 800 nm or less.

4. The method according to claim 1 , wherein the use amount of the tapping material defined as the cross-sectional area of tapping balls relative to the area of the metal sieve mesh is 1 to 70%.

5. The method according to claim 1 , wherein removal of electricity based on grounding with a ground resistance value of 100 SI or less is achieved in the classification step.

6. The method according to claim 1 , wherein the classification step is carried out under reduced pressure.

7. The method according to claim 1 , wherein the water absorbent resin after the surface crosslinking step has SFC (saline flow conductivity) value of 10 [×10 −7 cm 3 ·s·g −1 ] or greater, and/or moisture content of 0% to 3% by weight.

8. The method according to claim 1 , wherein the resin solid content of the water absorbent resin before being supplied to the surface crosslinking step is 85% to 99% by weight, and/or the water content of the moisture absorbent resin after the surface crosslinking step is 0.1% to 15% by weight.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 20, 2012
From: OKUDA, SUMIO; KANZAKI, SYUJI; ISHIZAKI, KUNIHIKO; FUJINO, SHINICHI; NOGI, KOZO
To: NIPPON SHOKUBAI CO., LTD.
Reel/Frame 029325/0560 →
Priority Claims (2)
JP 2010-061223 · Mar 17, 2010 · national
JP 2010-061224 · Mar 17, 2010 · national
Continuity (1)
Related Publication 20130066019A1 · Mar 14, 2013