Organic electroluminescence device and method for producing the same
An organic electroluminescence device including an anode, a cathode, an organic layer disposed between the anode and the cathode, the organic layer containing a hole injection layer, a hole transport layer and an emission layer containing a host material, wherein the hole injection layer, the hole transport layer and the emission layer each contain a phosphorescent light-emitting material, wherein the hole injection layer contains the phosphorescent light-emitting material in an amount of 10% by mass or more but less than 50% by mass, and wherein a concentration of the phosphorescent light-emitting material contained in the hole transport layer is lower than that in the hole injection layer, and a concentration of the phosphorescent light-emitting material contained in the emission layer is lower than that in the hole injection layer and higher than that in the hole transport layer.
1. An organic electroluminescence device comprising:
an anode,
a cathode,
an organic layer disposed between the anode and the cathode,
the organic layer containing a hole injection layer, a hole transport layer and an emission layer containing a host material,
wherein the hole injection layer, the hole transport layer and the emission layer each contain a phosphorescent light-emitting material,
wherein the phosphorescent light-emitting material in the hole injection layer, the hole transport layer and the emission layer are each the same,
wherein the hole injection layer contains the phosphorescent light-emitting material in an amount of 10% by mass or more but less than 50% by mass, and
wherein a concentration of the phosphorescent light-emitting material contained in the hole transport layer is lower than that in the hole injection layer, and a concentration of the phosphorescent light-emitting material contained in the emission layer is lower than that in the hole injection layer and higher than that in the hole transport layer,
wherein the host material is selected from the group consisting of a compound represented by General Formula (2) or General Formula (3):
where R represents a t-butyl group, a t-amyl group, a trimethylsilyl group, or a triphenylsilyl group, and R 1 to R 23 each represent a hydrogen atom, a C1-C5 alkyl group, a cyano group, a fluorine atom, a trifluoro group, a trimethylsilyl group, a triphenylsilyl group or a phenyl group;
where R represents a t-butyl group, a t-amyl group, a trimethylsilyl group, a triphenylsilyl group or a phenyl group, and R 1 to R 23 each represent a hydrogen atom, a C1-C5 alkyl group, a cyano group, a fluorine atom, a trifluoro group, a trimethylsilyl group, a triphenylsilyl group or a phenyl group, with the proviso that at least one of R, R 2 , R 4 , and R 16 , is a hydrogen.
2. The organic electroluminescence device according to claim 1 , wherein the hole transport layer further contains the host material.
3. The organic electroluminescence device according to claim 2 , wherein a ratio by mass of the phosphorescent light-emitting material to the host material in the emission layer is one to ten times a ratio by mass of the phosphorescent light-emitting material to the host material in the hole transport layer.
4. The organic electroluminescence device according to claim 1 , wherein the concentration of the phosphorescent light-emitting material contained in the hole transport layer is changed from an interface between the hole transport layer and the emission layer to an interface between the hole transport layer and the hole injection layer.
5. The organic electroluminescence device according to claim 2 , wherein the concentration of the host material contained in the hole transport layer is changed from an interface between the hole transport layer and the emission layer to an interface between the hole transport layer and the hole injection layer.
6. The organic electroluminescence device according to claim 1 , wherein at least one phosphorescent light-emitting material has an asymmetric structure.
7. The organic electroluminescence device according to claim 1 , wherein at least one phosphorescent light-emitting material is a compound represented by General Formula (1) below:
(L1) 2 -Ir-(L2) 1 General Formula (1)
where L1 denotes a ligand and L2 denotes a ligand different from L1.
8. The organic electroluminescence device according to claim 1 , wherein the hole injection layer further contains an arylamine derivative and an ionization potential of the arylamine derivative is 4.8 eV to 5.8 eV and wherein a difference between the ionization potential of the arylamine derivative and an ionization potential of the phosphorescent light-emitting material contained in the hole injection layer is within ±0.2 eV.
9. An organic electroluminescence device-producing method for producing the organic electroluminescence device according to claim 1 , comprising:
forming the hole injection layer, the hole transport layer and the emission layer through coating.
10. The organic electroluminescence device-producing method according to claim 9 , wherein the phosphorescent light-emitting material is soluble to a solvent used for the coating.
11. The organic electroluminescence device according to claim 1 , wherein the hole injection layer contains the phosphorescent light-emitting material in an amount of 25% by mass or more but less than 50% by mass.