Color filter array, method of manufacturing the same, and image sensor including the same

1. A color filter array comprising:

a color filter arrangement comprising a plurality of color filters disposed in an array on a substrate; and

an isolation wall disposed on the substrate, wherein the isolation wall is disposed in a same plane as the color filter arrangement and isolates each of the color filters from each other of the color filters and comprises a solid material comprising a plurality of air spaces therewithin;

wherein:

the isolation wall is formed of carbon nanotubes,

the color filter array further comprises a catalyst layer, formed using Fe(II)(CH 3 COO) 2 , disposed on the substrate, and

the carbon nanotubes of the isolation wall are grown on the catalyst layer.

2. The color filter array of claim 1 , wherein the plurality of air spaces occupies about 90% or more of the isolation wall by volume.

3. The color filter array of claim 1 , wherein the isolation wall is disposed on the substrate in a mesh shape and the plurality of color filters are disposed within openings in the mesh shape of the isolation wall.

4. The color filter array of claim 1 , wherein the carbon nanotubes are formed of silver, alumina, or carbon.

5. An image sensor comprising:

a detection element array comprising a two-dimensional (2D) array of detection elements; and

a color filter array comprising a plurality of color filters disposed on the detection element array in a 2D array corresponding to the 2D array of the detection element arrays,

wherein the color filter array comprises:

a color filter arrangement comprising a plurality of color filters, wherein each of the color filters transmits only light in a specific wavelength band;

an isolation wall which is disposed in a same plane as the color filter array and which isolates each of the color filters from each other of the color filters and comprises a solid material comprising a plurality of air spaces therewithin;

a transparent cover layer disposed on the color filter array; and

a plurality of color separation elements, wherein each of the color separation elements separates incident light into different wavelength bands, and wherein the plurality of color separations elements are disposed in a 2D array, within the transparent cover layer, such that light in each of the different wavelength bands is incident on a corresponding one of the plurality of color filters.

6. The image sensor of claim 5 , wherein the plurality of air spaces occupies about 90% or more of the isolation wall by volume.

7. The image sensor of claim 5 , wherein the isolation wall is formed in a mesh shape and the plurality of color filters are disposed within openings in the mesh shape of the isolation wall.

8. The image sensor of claim 5 , wherein the isolation wall is formed of nanotubes or solid nano coils formed of silver, alumina, or carbon.

9. The image sensor of claim 5 , further comprising a catalyst layer,

wherein the isolation wall is formed of carbon nanotubes grown on the catalyst layer.

10. The image sensor of claim 9 , wherein the catalyst layer is formed using a liquid catalytic material.

11. The image sensor of claim 10 , wherein the liquid catalytic material is Fe(II)(CH 3 COO) 2 as a catalytic material.

12. A method of manufacturing a color filter array, the method comprising:

forming a catalyst layer on a substrate;

patterning the a catalyst layer into a mesh shape by coating and patterning a photoresist on the catalyst layer;

forming a mesh-shaped isolation wall of a solid material comprising a plurality of air spaces by growing carbon nanotubes on the catalyst layer; and

forming a color filter arrangement comprising a plurality of color filters by disposing materials for the plurality of color filters in openings in the mesh-shaped isolation wall, such that the mesh-shaped isolation wall and the color filter arrangement are in a same plane and such that the mesh-shaped isolation wall isolates each of the color filters from each other of the color filters;

wherein the forming the catalyst layer comprises spin coating Fe(II)(CH 3 COO) 2 on the substrate.

13. The method of claim 12 , wherein the patterning the catalyst layer comprises using a tetramethylammonium hydroxide (TMAH, N(CH 3 ) 4 OH) as a developing solution.

14. The method of claim 12 , wherein the plurality of air spaces occupies about 90% or more of the isolation wall by volume.