Homogeneous mixtures for nanoparticle synthesis
Presented herein is a method for obtaining a dissolved selenium liquid mixture from solid selenium. The method involves mixing an amine solvent and a thiol solvent with the solid selenium to produce a liquid intermediate solution and removing a sulfur containing compound from the liquid intermediate solution to produce a dissolved selenium liquid mixture. A method for obtaining dissolved sulfur liquid mixture by mixing an amine with a thiol to produce a liquid solution that dissolves sulfur to produce a dissolved sulfur liquid mixture is also presented. In addition, a method for obtaining a dissolved sulfur and selenium liquid mixture from solid selenium and solid sulfur by mixing an amine solvent with a thiol solvent is presented.
1. A method for obtaining a dissolved selenium liquid mixture from solid selenium, comprising:
mixing an amine solvent and a thiol solvent with the solid selenium to produce a liquid intermediate solution; and
removing a sulfur containing compound from the liquid intermediate solution to produce a dissolved selenium liquid mixture.
2. The method of claim 1 , wherein the amine is a primary, a secondary, a tertiary amine, or a mixture thereof.
3. The method of claim 1 , wherein the amine is a diamine, a triamine, a compound with multiple amino groups, or a mixture thereof.
4. The method of claim 1 , wherein the amine is represented by
and the thiol is represented by R 4 -SH, wherein R 1 , R 2 , R 3 , and R 4 are independently selected from the group consisting of alkane, alkene, alkyne, functional groups, and hydrogen.
5. The method of claim 1 , wherein the sulfur containing compound is a thiol or a disulfide.
6. The method of claim 5 , wherein at least 99% of the sulfur containing compound is removed.
7. The method of claim 5 , wherein the sulfur containing compound is the thiol solvent.