Method for producing modified conjugated diene-based polymer, modified conjugated diene-based polymer, and modified conjugated diene-based polymer composition
A method for producing a modified conjugated diene-based polymer having a good balance between the hysteresis loss properties and the wet skid resistance, practically sufficient abrasion resistance and breaking strength, and high processability when formed into a vulcanized product is provided. A method for producing a modified conjugated diene-based polymer, comprising: a polymerization step of polymerizing a conjugated diene compound, copolymerizing conjugated diene compounds, or copolymerizing a conjugated diene compound with an aromatic vinyl compound using an alkali metal compound or an alkaline earth metal compound as a polymerization initiator to obtain a conjugated diene-based polymer having an active end, and a modifying step of reacting a compound represented by following formula (1) with the active end of the conjugated diene-based copolymer.
1. A modified conjugated diene-based polymer which comprises two silyl groups having an alkoxy group bonded thereto and which comprises a functional group including a secondary amino group within a molecule, wherein
a degree of modification is not less than 50% by mass, the degree of modification being determined by an amount to be adsorbed to a column filled with silica particles by gel permeation chromatography (GPC) measurement using the column,
the ratio (Mw/Mn) of the polystyrene equivalent weight average molecular weight (Mw) to the polystyrene equivalent number average molecular weight (Mn) by gel permeation chromatography (GPC) measurement in the modified conjugated diene-based polymer is not less than 1.80 and not more than 3.50, and
the Mooney stress-relaxation rate (MSR) of the modified conjugated diene-based polymer measured at 110° C. is not more than 0.35.
2. The modified conjugated diene-based polymer according to claim 1 , wherein a polystyrene equivalent number average molecular weight (Mn) of the modified conjugated diene-based polymer measured by gel permeation chromatography (GPC) is from 200,000 to 600,000.
3. A modified conjugated diene-based polymer composition comprising:
100 parts by mass of a rubber component containing not less than 20 parts by mass of a modified conjugated diene-based polymer according to claim 1 , and
0.5 to 300 parts by mass of a silica-based inorganic filler.
4. A modified conjugated diene-based polymer composition comprising:
100 parts by mass of a rubber component containing not less than 20 parts by mass of a modified conjugated diene-based polymer according to claim 2 , and
0.5 to 300 parts by mass of a silica-based inorganic filler.
5. A modified conjugated diene-based polymer composition comprising:
100 parts by mass of a rubber component containing not less than 20 parts by mass of a modified conjugated diene-based polymer according to claim 1 , and
0.5 to 300 parts by mass of a silica-based inorganic filler.