Polyester resin and method for preparing the same
A polyester resin copolymerized with isosorbide and 1,4-cyclohexane dimethanol and having an improved impact strength, and a method for preparing the same are disclosed. The copolymerized polyester resin has an alternating structure of acid moieties which are derived from acid components and diol moieties which are derived from diol components, wherein the acid components comprise terephthalic acid, and the diol components comprise (i) 5˜99 mol % of 1,4-cyclohexanedimethanol and (ii) 1˜60 mol % of isosorbide with respect to the total diol components.
1. A method for preparing polyester resin, comprising the steps of:
carrying out an esterification reaction or a trans-esterification reaction of acid components and diol components at the increased pressure of 0.2˜3.0 kg/cm 2 and the temperature of 240˜300° C. during an average retention time of 2˜10 hours; and
carrying out a polycondensation reaction for a product of the esterification reaction or the trans-esterification reaction at the reduced pressure of 400˜0.1 mmHg and at the temperature of 240˜300° C. during an average retention time of 1˜10 hours,
wherein the acid components comprise terephthalic acid, and the diol components comprise (i) 42˜58 mol % of 1,4-cyclohexanedimethanol and (ii) 19˜40 mol % of isosorbide with respect to the total diol components, and
a glass transition temperature (Tg) of the polyester resin is more than 104° C., and notch izod impact strength of the polyester resin is more than 129 J/m.
2. The method for preparing polyester resin according to claim 1 , wherein the amount of isosorbide (ISB mol %) is in the range of the following Equation 1,
0.0012(CHDM mol %) 2 −0.2401(CHDM mol %)+14.136<=ISB mol %<=0.0049(CHDM mol %) 2 −0.2255(CHDM mol %)+71.176 [Equation 1]
wherein CHDM mol % represents the amount of 1,4-cyclohexane dimethanol.