Manufacturing method of porous polymer film using vanadium oxide nanowire, and porous polymer film prepared therefrom
This patent is provided a method for producing a porous polymer film using vanadium oxide nanowires, and a porous polymer film obtained from the method. The method allows control of a uniform pore size and density through a simple process including the steps of: adding an ion exchanger to deionized water to perform acidification and adding a vanadate compound thereto to grow vanadium oxide nanowires by a sol-gel process; mixing the resultant solution of grown nanowires with a polymer solution to provide a mixed solution of nanowires; pouring the mixed solution of nanowires to a mold, followed by drying and curing, to form a film; and etching the resultant film with an etching solution to remove the vanadium oxide nanowires.
1. A method for producing a porous polymer film using vanadium oxide nanowires as a template to allow control of a uniform pore size and density of the porous polymer film, the method comprising the steps of:
(A) adding an ion exchanger to deionized water to perform acidification to a pH of 2.0-2.5 and adding a vanadate compound thereto to grow vanadium oxide nanowires by a sol-gel process, producing a resultant solution of grown nanowires;
(B) mixing the resultant solution of grown nanowires with a polymer solution and a surfactant to provide a mixed solution of nanowires;
(C) pouring the mixed solution of nanowires to a mold, followed by drying and curing, to form a film; and
(D) etching the resultant film with an etching solution to remove the vanadium oxide nanowires,
wherein the polymer solution is provided in step (B) in an amount of 10-30 parts by weight per part by weight of the vanadate compound,
wherein the surfactant is mixed in an amount of 10-70 parts by weight based on 100 parts by weight of the polymer solution, and
wherein the pores in the porous polymer film have a rectangular column shape.
2. The method according to claim 1 , wherein the vanadate compound and ion exchanger are mixed in a weight ratio of 1:5-30, in step (A).
3. The method according to claim 1 , wherein the vanadate compound is ammonium (meta)vanadate or sodium vanadate, in step (A).
4. The method according to claim 1 , wherein the polymer solution comprises a polymer selected from the group consisting of a polyurethane, polyethylene, polysulfone, polyvinylidene fluoride, and copolymers thereof, in step (B).
5. The method according to claim 1 , wherein the pores are formed to have a width of 2-8 nm, a length of 10-30 nm and a height of 15-50 μm.
6. A porous polymer film obtained by the method as defined in claim 1 .
7. The method according to claim 1 , wherein the vanadium oxide nanowires are grown at a temperature ranging from 45-55° C.