Semiconductor device
A semiconductor device of an embodiment includes an n-type SiC region, a metal layer, and a conductive layer provided between the n-type SiC region and the metal layer, the conductive layer including titanium (Ti), oxygen (O), at least one first element from zirconium (Zr) and hafnium (Hf), and at least one second element from vanadium (V), niobium (Nb), and tantalum (Ta).
1. A semiconductor device comprising:
an n-type SiC region;
a metal layer; and
a conductive layer provided between the n-type SiC region and the metal layer, the conductive layer including titanium (Ti), oxygen (O), at least one first element from zirconium (Zr) and hafnium (Hf), and at least one second element from vanadium (V), niobium (Nb), and tantalum (Ta).
2. The device according to claim 1 , wherein an atomic ratio of titanium to sum of titanium, zirconium, and hafnium in the conductive layer (Ti/(Ti+Zr+Hf)) is equal to or greater than 0.5 and equal to or less than 0.8.
3. The device according to claim 1 , wherein a concentration of the at least one second element in the conductive layer is equal to or greater than 1×10 19 cm −3 .
4. The device according to claim 1 , wherein the conductive layer contains metal oxide.
5. The device according to claim 1 , wherein a concentration of an n-type impurity of the n-type SiC region is equal to or greater than 1×10 19 cm −3 .
6. The device according to claim 1 , further comprising a p-type SiC region, wherein the metal layer is in contact with the p-type SiC region and the conductive layer.
7. A semiconductor device comprising:
an n-type SiC region;
a metal layer; and
a conductive layer provided between the n-type SiC region and the metal layer, the conductive layer including titanium (Ti), oxygen (O), at least one first element from zirconium (Zr) and hafnium (Hf), at least one metal element from calcium (Ca), strontium (Sr), and barium (Ba), and at least one second element from vanadium (V), niobium (Nb), tantalum (Ta), scandium (Sc), yttrium (Y), and lanthanoid.
8. The device according to claim 7 , wherein an atomic ratio of titanium to sum of titanium, zirconium, and hafnium in the conductive layer (Ti/(Ti+Zr+Hf)) is equal to or greater than 0.5 and equal to or less than 0.8.
9. The device according to claim 7 , wherein a concentration of the at least one second element in the conductive layer is equal to or greater than 1×10 19 cm −3 .
10. The device according to claim 7 , wherein the conductive layer contains metal oxide.
11. The device according to claim 7 , wherein the conductive layer contains calcium titanate, strontium titanate, or barium titanate.
12. The device according to claim 7 , wherein a concentration of an n-type impurity of the n-type SiC region is equal to or greater than 1×10 19 cm −3 .
13. The device according to claim 7 , further comprising a p-type SiC region, wherein the metal layer is in contact with the p-type SiC region and the conductive layer.
14. The device according to claim 7 , wherein the conductive layer contains lead (Pb).
15. The device according to claim 7 , wherein temperature dependency of electric resistance of the conductive layer turns from negative dependency to positive dependency at a temperature equal to or greater than 150° C. and equal to or less than 200° C.