Resin-metal bonded body and method for producing the same
Disclosed is a resin-metal bonded body of an aluminum metal member and a thermoplastic resin member, which has improved bonding strength and good durability. Also disclosed is a method for producing such a resin-metal bonded body. Specifically disclosed is a resin-metal bonded body which is obtained by bonding an aluminum metal member with a thermoplastic resin member. In this resin-metal bonded body, the aluminum metal member and the thermoplastic resin member are bonded together by an anodic oxide coating having a film thickness of 70-1500 nm or an anodic oxide coating having a triazine thiol in the inner and upper portions. The anodic oxide coating has an infrared absorption spectrum peak intensity ascribed to OH group at 0.0001-0.16.
1. A method for producing a resin-metal bonded body, comprising:
an anodic oxidation step of forming an anodic oxide coating having a coating thickness of 70-1500 nm on an aluminum metal member through electrolysis with a current density of 0.02 A/dm 2 or higher and less than 2.5 A/dm 2 in at least one of an acid solution selected from the group consisting of sulfuric acid, chromic acid, oxalic acid, and phosphoric acid at 50-90° C. using the aluminum metal member as an anode;
a water washing step of washing the aluminum metal member with water at a temperature of 5° C. or higher and less than 60° C. so as to obtain an infrared absorption spectrum peak intensity of the anodic oxide coating ascribed to the OH group at 0.0001-0.16; and
a step of insert molding a thermoplastic resin on the aluminum metal member after the water washing step, so that said aluminum metal member and the thermoplastic resin are bonded together only by the anodic oxide coating, to have a strength of initial adhesion of 40 MPa or more.