Resin composition for optical material, optical film, and liquid crystal display device

Inventors: Teppei Ujihara (Ichihara, JP); Yusuke Tajiri (Ichihara, JP); Masato Ishiyama (Ichihara, JP)

Assignee: DIC CORPORATION

G02B1/04 C08L67/02 C08L69/00 G02B1/14 G02F1/133528

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Quick Facts

Patent No.: US 9,690,010
App. No.: 15/022,094
Granted: Jun 27, 2017
Kind: B2

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Abstract

For providing a resin composition for an optical material which exhibits less change in birefringence due to external force and which is suitable for use in the production of an optical member; an optical film obtained by using the resin composition; and a liquid crystal display device using the same, provided is a resin composition containing a polycarbonate resin (X); and a polyester resin (Y) whose number average molecular weight is 200 to 2,000 and which is represented by General Formula (1): B-(G-A) n -G-B (wherein B represents an aryl monocarboxylic acid residue having 6 to 12 carbon atoms or an aliphatic monocarboxylic acid residue having 1 to 8 carbon atoms.

Claims (36)

1. A resin composition for an optical material, comprising:

a polycarbonate resin (X); and

a polyester resin (Y) whose number average molecular weight is from 200 to 2,000 and which is represented by General Formula (1) shown below:

B-(G-A) n -G-B (1)

wherein B represents an aryl monocarboxylic acid residue having 6 to 12 carbon atoms or an aliphatic monocarboxylic acid residue having 1 to 8 carbon atoms, G represents an alkylene glycol residue having 2 to 12 carbon atoms or an oxyalkylene glycol residue having 4 to 12 carbon atoms, A represents an alkylene dicarboxylic acid residue having 2 to 12 carbon atoms or an aryl dicarboxylic acid residue having 6 to 12 carbon atoms, and n is an integer of 0 to 9; and

wherein the polycarbonate resin (X) and the Polyester resin (Y) are mixed or blended together to form the resin composition.

2. The resin composition for an optical material according to claim 1 ,

wherein, in the polyester resin (Y), B represents a benzene monocarboxylic acid residue, G represents an alkylene glycol residue having 2 to 6 carbon atoms, A represents an alkylene dicarboxylic acid residue having 2 to 6 carbon atoms or an aryl dicarboxylic acid residue having 6 to 12 carbon atoms, and n is an integer of 1 to 9.

3. The resin composition for an optical material according to claim 2 ,

wherein, in General Formula (1), B represents a benzoic acid residue, G represents a propylene glycol residue, and A represents a phthalic acid residue, a cyclohexane dicarboxylic acid residue or an adipic acid residue.

4. The resin composition for an optical material according to claim 1 ,

wherein, in the polyester resin (Y), B represents a benzene monocarboxylic acid residue or an alicyclic monocarboxylic acid residue having 6 to 8 carbon atoms, G represents an alkylene glycol residue having 2 to 6 carbon atoms, and n is 0.

5. The resin composition for an optical material according to claim 4 ,

wherein, in the polyester resin (Y), B represents a benzoic acid residue, a paratoluic acid residue or a cyclohexane carboxylic acid residue, and G represents a propylene glycol residue, a neopentyl glycol residue, a butanediol residue or a hexanediol residue.

6. The resin composition for an optical material according to claim 1 ,

wherein the number average molecular weight of the polyester resin (Y) is from 250 to 1,000.

7. The resin composition for an optical material according to claim 1 ,

wherein the content of the polyester resin (Y) is from 0.5 to 10 parts by mass with respect to 100 parts by mass of the polycarbonate resin (A).

8. The resin composition for an optical material according to claim 1 ,