Method for preparing super absorbent polymer
This disclosure relates to a method for preparing super absorbent polymer. The method for preparing super absorbent polymer according to the present invention comprises the steps of performing photopolymerization of a monomer composition comprising water soluble ethylene unsaturated monomers, a thermal polymerization initiator and a photopolymerization initiator at a temperature of 30 to 55° C.; performing a thermal polymerization and a photopolymerization at a temperature of 55 to 120° C. to form a hydrogel polymer; and drying the hydrogel polymer. According to the present invention, by comprising two polymerization steps including performing photopolymerization at low temperature and then performing thermal polymerization or photopolymerization at high temperature, super absorbent polymer having improved physical properties may be obtained.
1. A method for preparing super absorbent polymer comprising the steps of:
performing photopolymerization of a monomer composition comprising water soluble ethylene unsaturated monomers, a thermal polymerization initiator and a photopolymerization initiator at a temperature of 30 to 55° C.;
performing a thermal polymerization and a photopolymerization at a temperature of 55 to 120° C. to form a hydrogel polymer; and
drying the hydrogel polymer,
wherein the temperature of the monomer composition reaches 55° C. or more in the step of performing photopolymerization of the monomer composition, and the thermal polymerization is progressed at the temperature of 55° C. or more.
2. The method according to claim 1 , wherein the thermal polymerization initiator includes at least one selected from the group consisting of persulfate initiators, azo initiators, hydrogen peroxide, and ascorbic acid.
3. The method according to claim 1 , wherein the photopolymerization initiator includes at least one selected from the group consisting of benzoin ether, dialkyl acetophenone, hydroxyl alkylketone, phenyl glyoxylate, benzyl dimethyl ketal, acyl phosphine and α-aminoketone.
4. The method according to claim 1 , wherein the hydrogel polymer has a moisture content of 40 to 80%, before drying the hydrogel polymer.
5. The method according to claim 1 , further comprising the step of pulverizing the hydrogel polymer to a particle diameter of 2 to 10 mm, before drying the hydrogel polymer.
6. The method according to claim 1 , wherein the drying of the hydrogel polymer is performed at a temperature of 150 to 250° C.
7. The method according to claim 1 , further comprising the steps of
pulverizing the dried polymer; and
performing a surface crosslinking reaction of a pulverized polymer.
8. The method according to claim 7 , wherein the pulverization of the dried polymer is progressed to a particle diameter of 150 to 850 μm.
9. The method according to claim 7 , further comprising the step of classifying the pulverized polymer into a polymer having a particle diameter of 150 to 850 μm, before the surface crosslinking reaction.
10. The method according to claim 1 , wherein the super absorbent polymer has a centrifuge retention capacity of 34 to 37 g/g, an absorption capacity under pressure of 24 to 27 g/g, and a water soluble component content of 11 to 13 wt %.