Electrode material and method for manufacturing same
An electrode material including electrode active material particles and a carbonaceous film layer coating surfaces of the electrode active material particles and including a metal oxide, a content ratio of the metal oxide in the carbonaceous film layer being 5% by mass to 70% by mass. A method for manufacturing an electrode material, in which electrode active material particles, a metal salt or metal alkoxide containing any one or more metal atoms selected from a group consisting of Al, Zr, Si, and Ti, and an organic compound which is a precursor of carbon are mixed so that a total blending amount of the metal salt or metal alkoxide satisfies that an amount of a metal oxide in the carbonaceous film layer when the metal salt or metal alkoxide is all changed to the metal oxide is 5% by mass to 70% by mass, and are heated in a non-oxidative atmosphere.
1. An electrode material comprising:
electrode active material particles; and a carbonaceous film layer which coats surfaces of the electrode active material particles and includes a metal oxide,
wherein a content ratio of the metal oxide in the carbonaceous film layer is in a range of 5% by mass to 70% by mass,
wherein the metal oxide is made of at least one selected from a group consisting of Al 2 O 3 , ZrO 2 , SiO 2 , and TiO 2 ,
wherein the electrode active material particles are represented by Li x A y D z PO 4 (here, A represents one or more selected from the group consisting of Co, Mn, Ni, Fe, Cu, and Cr, D represents one or more selected from the group consisting of Mg, Ca, Sr, Ba, Ti, Zn, B, Al, Ga, In, Si, Ge, Sc, Y, and rare earth elements, 0<x<1.2, 0<y≦1, 0≦z<1.5, and 0.9<y≦1),
wherein the carbonaceous film layer is a single layer in which the metal oxide is uniformly disposed in carbon.
2. The electrode material according to claim 1 ,
wherein an amount of carbon is in a range of 0.6 parts by mass to 4.0 parts by mass with respect to 100 parts by mass of the electrode active material particles.
3. The electrode material according to claim 1 ,
wherein an amount of carbon is in a range of 0.9 parts by mass to 1.2 parts by mass with respect to 100 parts by mass of the electrode active material particles.
4. A method for manufacturing an electrode material comprising electrode active material particles and a carbonaceous film layer which coats surfaces of the electrode active material particles,
wherein electrode active material particles,
a metal salt or metal alkoxide containing any one or more metal atoms selected from a group consisting of Al, Zr, Si, and Ti, and
an organic compound which is a precursor of carbon
are mixed so that a total blending amount of the metal salt or metal alkoxide satisfies that an amount of a metal oxide included in the carbonaceous film layer when the metal salt or metal alkoxide is all changed to the metal oxide falls in a range of 5% by mass to 70% by mass, and are heated in a non-oxidative atmosphere,
wherein the metal oxide is made of at least one selected from a group consisting of Al 2 O 3 , ZrO 2 , SiO 2 , and TiO 2 ,
wherein the electrode active material particles are represented by Li x A y D z PO 4 (here, A represents one or more selected from the group consisting of Co, Mn, Ni, Fe, Cu, and Cr, D represents one or more selected from the group consisting of Mg, Ca, Sr, Ba, Ti, Zn, B, Al, Ga, In, Si, Ge, Sc, Y, and rare earth elements, 0<x<1.2, 0<y≦1, 0≦z<1.5, and 0.9<y+z≦1).
5. The method for manufacturing an electrode material according to claim 4 ,
wherein the total blending amount of the organic compound is in a range of 0.6 parts by mass to 4.0 parts by mass with respect to 100 parts by mass of the electrode active material particles when the total blending amount is converted to an amount of carbon.