Binder composition for secondary battery, cathode and lithium battery including the binder composition
In an aspect, a binder composition for a secondary battery including a first fluoropolymer binder containing a polar functional group; a second fluoropolymer binder that does not contain a polar functional group; and a non fluoropolymer binder is provided.
1. A binder composition for a secondary battery, the binder composition comprising:
a first fluoropolymer binder comprising a polar functional group;
a second fluoropolymer binder that does not comprise a polar functional group; and
a non fluoropolymer binder comprising a repeating unit derived from an acryl monomer,
wherein the first fluoropolymer binder is a vinylidene fluoride binder.
2. The binder composition of claim 1 , wherein the polar functional group of the first fluoropolymer binder comprises at least one selected from the group consisting of a carboxylic acid group, a sulfonic acid group, a phosphoric acid group, and a hydroxy group, or a salt of the group.
3. The binder composition of claim 1 , wherein an amount of a repeating unit comprising the polar functional group in the first fluoropolymer binder is 10 mol % or less.
4. The binder composition of claim 1 , wherein a weight average molecular weight of the first fluoropolymer binder is 300,000 g/mol or more.
5. The binder composition of claim 1 , wherein the first fluoropolymer binder comprises:
a repeating unit derived from a monomer containing a polar functional group;
a repeating unit derived from a vinylidene fluoride; and
optionally, a repeating unit derived from at least one fluorine-containing monomer selected from the group consisting of tetrafluoroethylene, hexafluoropropylene, chlorotrifluoroethylene, fluorovinyl, and perfluoroalkylvinylether.
6. The binder composition of claim 1 , wherein an amount of the first fluoropolymer binder is in a range of about 3 weight % to about 27 weight % based on a total weight of the binder composition.
7. The binder composition of claim 1 , wherein the second fluoropolymer binder is a vinylidene fluoride binder that does not comprise a polar functional group.
8. The binder composition of claim 1 , wherein a weight average molecular weight of the second fluoropolymer binder is 300,000 g/mol or more.
9. The binder composition of claim 1 , wherein an amount of the second fluoropolymer binder is in a range of about 45 weight % to about 82 weight % based on a total weight of the binder composition.
10. The binder composition of claim 1 , wherein the non fluoropolymer binder comprises a repeating unit derived from an acryl monomer.
11. The binder composition of claim 1 , wherein the repeating unit derived from an acryl monomer in the non fluoropolymer binder comprises a nitrile group.
12. The binder composition of claim 1 , wherein the repeating unit derived from an acryl monomer in the non fluoropolymer binder comprises a carboxyl group.
13. The binder composition of claim 1 , wherein a weight average molecular weight of the non fluoropolymer binder is 100,000 g/mol or more.
14. The binder composition of claim 1 , wherein a glass transition temperature of the non fluoropolymer binder is in a range of −40° C. to 30° C. g/mol or more.
15. The binder composition of claim 1 , wherein an amount of the non fluoropolymer binder is in a range of about 5 weight % to about 30 weight % based on a total weight of the binder composition.
16. A cathode comprising:
a cathode active material; a conductive agent; and
the binder composition of claim 1 .
17. The cathode of claim 16 , wherein an amount of the binder composition is in a range of about 0.5 to about 5 parts by weight based on 100 parts by weight of the cathode active material.
18. The cathode of claim 16 , wherein a weight of a cathode mixture per unit area of the cathode is higher than 54.0 mg/cm 2 .
19. A lithium battery comprising: the cathode of claim 16 ; an anode; and a separator.
20. The lithium battery of claim 19 , wherein a voltage of the lithium battery is 4.0 V or more.