IP Library › Granted Patent US 9,724,568
Granted Patent B2
US 9,724,568 · App. 14/984,755 · Granted Aug 8, 2017

Golf ball

Inventors: Kae Yamazaki (Saitamaken, JP); Tsuyoshi Nakajima (Saitamaken, JP); Yuichiro Ozawa (Saitamaken, JP)
Assignee: Bridgestone Sports Co., Ltd.
A63B37/0074A63B37/006A63B37/0051A63B37/0063A63B37/0064A63B37/0065A63B37/0066A63B37/0068A63B37/0075A63B37/0076C08L21/00
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Quick Facts
Patent No.
US 9,724,568
App. No.
14/984,755
Granted
Aug 8, 2017
Kind
B2
Abstract

The invention provides a golf ball having a core and a cover of one layer or a plurality of layers, wherein the core is formed of a material molded under heat from a rubber composition containing (A) a base rubber, (B) an organic peroxide, and (C) water and/or a metal monocarboxylate, and has a hysteresis loss of 50% or less when compressed at a load cell speed of 500 mm/min and under a constant load of 5,000 N.

Claims (19)

1. A golf ball comprising a core and a cover of one layer or a plurality of layers, wherein the core is formed of a material molded under heat from a rubber composition comprising the following components A to C:

(A) a base rubber,

(B) an organic peroxide, and

(C) water and/or a metal monocarboxylate,

and has a hysteresis loss of 50% or less when compressed at a load cell speed of 500 mm/min and under a constant load of 5,000 N.

2. The golf ball of claim 1 , wherein the core has a JIS-C hardness difference obtained by subtracting a hardness at the center of the core from a hardness at a surface of the core which is at least 20.

3. The golf ball of claim 1 , wherein the core has a hardness at an interior thereof such that a value obtained by subtracting a JIS-C hardness H 5.0 at a position 5.0 mm outward from a center of the core and towards a periphery of the core from a JIS-C hardness H 15.0 at a position 15.0 mm outward from the core center and toward the core periphery is a positive value.

4. The golf ball of claim 1 , wherein the core has a diameter of not more than 42.0 mm and a deflection when compressed under a final load of 1,275 N (130 kgf) from an initial load state of 98 N (10 kgf) of from 2.0 to 6.0 mm.

5. The golf ball of claim 1 , wherein the rubber composition before vulcanization has a moisture content of at least 1,000 ppm.

6. The golf ball of claim 1 , wherein the rubber composition includes from 0.1 to 5 parts by weight of an organosulfur compound per 100 parts by weight of the base rubber.

7. The golf ball of claim 1 , wherein the core after vulcanization has a higher moisture content at a center of the core than at a surface of the core.

8. The golf ball of claim 1 , wherein a product P×E of a difference P (mol/m 3 ) in crosslink density between a surface of the core and a center of the core, as measured based on a toluene swelling test, multiplied by a deflection E (mm) of the core when compressed under a final load of 1,275N (130 kgf) from an initial load state of 98N (10 kgf) is at least 28×102 mol/m 3 *mm.

9. The golf ball of claim 1 , wherein, when a loss tangent of a center of the core is measured at a temperature of −12° C. and a frequency of 15 Hz, letting tan δ 1 be a loss tangent at a dynamic strain of 1% and tan δ 10 be a loss tangent at a dynamic strain of 10%, the slope of these tan δ values, expressed as [(tan δ 10 −tan δ 1 )/(10%−1%)], is not more than 0.003.

10. The golf ball of claim 1 , wherein each layer of the cover has a thickness in a range from 0.5 to 2.5 mm.

11. The golf ball of claim 1 , wherein at least one layer of the cover is formed of a resin composition containing at least one of (I) and (II) below:

(I) an ionic or nonionic olefin-unsaturated carboxylic acid copolymer,

(II) an ionic or nonionic olefin-unsaturated carboxylic acid-carboxylic acid ester copolymer.

12. The golf ball of claim 11 , wherein copolymers (I) and (II) have a base monomer that is ethylenic.

13. The golf ball of claim 11 , wherein the carboxylic acid in ionic copolymers (I) and (II) is at least 30 mol % neutralized.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 30, 2016
From: YAMAZAKI, KAE; NAKAJIMA, TSUYOSHI; OZAWA, YUICHIRO
To: BRIDGESTONE SPORTS CO., LTD. OF WORLD TRADE CENTER BUILDING
Reel/Frame 038141/0666 →
Continuity (3)
Continuation In Part 14934445 · Nov 6, 2015
Continuation 14016801 · Sep 3, 2013
Related Publication 20160184655A1 · Jun 30, 2016