Electrode having active material encased in conductive net
An anode for a lithium-ion battery includes a current collector, a separator and an active material comprising alloying particles and a carbon material. A conductive net of carbon material surrounds the active material on at least the side walls and a separator-facing surface, the conductive net having net openings sized to retain the alloying particles and the carbon material within the conductive net while allowing lithium ions and electrons to pass through. The conductive net also maintains electrical contact between the carbon material and the alloying particles during lithiation and delithiation of the alloying particles.
1. An anode for a lithium-ion battery comprising:
a current collector;
a separator;
an active material layer between the current collector and the separator having a collector-facing surface, a separator-facing surface and side walls extending around a perimeter of the active material layer, the active material layer comprising alloying particles and a carbon material; and
a conductive net of carbon material surrounding the active material layer on at least the side walls of the active material layer and the separator-facing surface of the active material layer, the conductive net having net openings sized to retain the alloying particles and the carbon material within the conductive net while allowing lithium ions and electrons to pass through, the conductive net maintaining electrical contact between the carbon material and the alloying particles during lithiation and delithiation of the alloying particles.
2. The anode of claim 1 , wherein the alloying particles comprise one or more of silicon, tin and germanium.
3. The anode of claim 1 , wherein the conductive net is a carbon cloth.
4. The anode of claim 1 , wherein the conductive net surrounds all sides of the active material layer, the conductive net in direct contact with the current collector and spaced from the separator.
5. The anode of claim 4 , wherein the net openings have a first size on the side walls and a second size on the separator-facing surface and the collector-facing surface, the first size different from the second size.
6. The anode of claim 5 , wherein in the first size is smaller than the second size.
7. The anode of claim 1 , wherein the conductive net is formed of carbon black, graphene, or carbon nanotubes.
8. The anode of claim 1 , wherein the net openings are uniform is size across all surfaces.
9. The anode of claim 1 , wherein the net openings have a first size on the side walls and a second size on the separator-facing surface, the first size different from the second size.
10. The anode of claim 9 , wherein the first size is smaller than the second size.
11. The anode of claim 1 , further comprising a conductive adhesive between the active material layer and the conductive net.
12. The anode of claim 1 further comprising:
a buffer layer coated on the current collector, wherein the active material layer is coated on the buffer layer and the conductive net is formed on the remaining surfaces of the active material layer.
13. The anode of claim 12 , wherein the buffer layer is a conductive material that is chemically inert, the buffer layer configured to buffer the current collector from expansion of the alloying particles during lithiation.
14. A lithium ion battery comprising the anode of claim 1 .
15. An anode for a lithium-ion battery comprising:
a current collector;
a separator;
an active material layer comprising alloying particles and a carbon material; and
a conductive net of carbon material surrounding the active material layer surrounding all sides of the active material layer, the conductive net in direct contact with the current collector and spaced from the separator, the conductive net having net openings sized to retain the alloying particles and the carbon material within the conductive net while allowing lithium ions and electrons to pass through, the conductive net maintaining electrical contact between the carbon material and the alloying particles during lithiation and delithiation of the alloying particles, wherein the net openings have a first size on side walls and a second size on a separator-facing surface and a collector-facing surface, the first size different from the second size.
16. An anode for a lithium-ion battery comprising:
a current collector;
a separator;
an active material layer comprising alloying particles and a carbon material; and
a conductive net of carbon material on at least side walls of the active material layer and a separator-facing surface of the active material layer, the conductive net in direct contact with the current collector and spaced from the separator, the conductive net having net openings sized to retain the alloying particles and the carbon material within the conductive net while allowing lithium ions and electrons to pass through, the conductive net maintaining electrical contact between the carbon material and the alloying particles during lithiation and delithiation of the alloying particles, wherein the net openings have a first size on the side walls and a second size on the separator-facing surface, the first size different from the second size.