Piezoelectric thin film and method for producing the same
A piezoelectric thin film is formed through sputtering and consists essentially of scandium aluminum nitride. The carbon atomic content is 2.5 at % or less. When producing the piezoelectric thin film, scandium and aluminum are sputtered simultaneously on a substrate from a scandium aluminum alloy target material having a carbon atomic content of 5 at % or less in an atmosphere where at least nitrogen gas exists. The sputtering may be conducted also by applying an ion beam on an opposing surface of the alloy target material at an oblique angle. Moreover, aluminum and scandium may be also sputtered simultaneously on the substrate from an Sc target material and an Al target material. As a result, a piezoelectric thin film which exhibits excellent piezoelectric properties and a method for the same can be provided.
1. A piezoelectric thin film that is formed through sputtering and consists essentially of scandium aluminum nitride, wherein
the piezoelectric thin film has a carbon atomic content between 0.1 at % and 2.5 at %.
2. The piezoelectric thin film according to claim 1 , wherein
the carbon atomic content of the piezoelectric thin film is between 0.1 at % and 1.5 at %.
3. The piezoelectric thin film according to claim 1 , wherein
the carbon atomic content of the piezoelectric thin film is between 0.1 at % and 0.75 at %.
4. A method for producing the piezoelectric thin film according to claim 1 , the method comprising:
a single-target sputtering step of producing the piezoelectric thin film by simultaneously sputtering scandium and aluminum on a substrate from an alloy target material consisting essentially of a scandium aluminum alloy having a carbon content of 0.2 through 5.0 at % under an atmosphere where at least nitrogen gas exists.
5. The method for producing the piezoelectric thin film according to claim 4 , wherein
the alloy target material consists essentially of a scandium aluminum alloy having a carbon atomic content of 3 at % or less.
6. The method for producing the piezoelectric thin film according to claim 4 , wherein
the alloy target material consists essentially of a scandium aluminum alloy having a carbon atomic content of 1.5 at % or less.
7. A method for producing the piezoelectric thin film according to claim 1 , the method comprising:
a two-target sputtering step of producing the piezoelectric thin film by simultaneously sputtering aluminum and scandium on a substrate from an Sc target material consisting essentially of scandium having a carbon atomic content of 0.2/x through 5/x at % and an Al target material consisting essentially of aluminum under an atmosphere where at least nitrogen gas exists, wherein
the piezoelectric thin film consists essentially of scandium aluminum nitride represented by a general formula Sc x Al 1-x N (0<x<1).
8. The method for producing the piezoelectric thin film according to claim 7 , wherein
the Sc target material consists essentially of scandium having a carbon atomic content of 3/x at % or less.
9. The method for producing the piezoelectric thin film according to claim 7 , wherein
the Sc target material consists essentially of scandium having a carbon atomic content of 1.5/x at % or less.
10. A piezoelectric thin film consisting essentially of scandium aluminum nitride including carbon in an amount of 0.1 at % through 2.5 at %, wherein the piezoelectric thin film is prepared by a method comprising:
an ion irradiation sputtering step of producing the piezoelectric thin film by
arranging a surface of an alloy target material to face a substrate, the alloy target material consisting essentially of a scandium aluminum alloy including a carbon content of 10 at % or less,
applying, at an oblique angle, an ion beam to the surface of the alloy target material facing the substrate, and
simultaneously sputtering scandium and aluminum on the substrate from the alloy target material, wherein
during the ion irradiation sputtering step, the ion beam including at least a nitrogen ion is applied or the ion beam is applied under an atmosphere where at least nitrogen gas exists.