Plate-type reactor with in-situ injection
A chemical reactor including: a plurality of heat exchange plates which between them define reaction compartments, in which reactor each heat exchange plate includes two walls between them defining at least one heat exchange space, the respective walls being fixed together by joining regions, and the reactor also comprises at least one injection device for injecting substance into the reaction compartments, said substance-injection device passing through the heat-exchange plates in respective joining regions thereof. Also, a chemical reaction process that can be carried out in this reactor.
1. A chemical reaction process comprising:
admission of reactants at an inlet of a reaction compartment defined between two heat-exchange plates,
withdrawal of reaction products at an outlet of the reaction compartment, and
injection of a substance into the reaction compartment,
wherein each heat-exchange plate comprises two walls defining, between them, at least one heat-exchange space, the respective walls being fixed to one another by joining regions, and the injection of substance being carried out by means of at least one substance-injecting device which passes through openings in the heat-exchange plates in respective joining regions of the plates,
wherein the reaction is of a heterogeneous catalytic type and a catalyst is positioned in the reaction compartment, and
wherein the process further comprises alternate phases of production and phases of regeneration of the catalyst, the injection of substance being carried out during the reaction phases in order to conduct a catalytic reaction in the reaction compartment and/or during the regeneration phases in order to regenerate the catalyst in the reaction compartment.
2. The process as claimed in claim 1 , wherein the substance is a reactant or a catalytic compound or a compound capable of regenerating a catalyst.
3. The process as claimed in claim 1 , wherein the substance is an oxygen-comprising gas.
4. The process as claimed in claim 1 , wherein the substance is injected at several points of the route of the reactants in the reaction compartment.
5. The process as claimed in claim 1 , wherein the process is carried out in a chemical reactor.
6. The process as claimed in claim 1 , wherein the process is:
a process for dehydration of glycerol to give acrolein; or
a process for dehydration of lactic acid to give acrylic acid; or
a process for dehydration of 3-hydroxypropionic acid to give acrylic acid; or
a process for dehydration of 3-hydroxyisobutyric acid to give methacrylic acid; or
a process for dehydration of 2-hydroxyisobutyric acid to give methacrylic acid; or
a process for conversion of a chlorinated compound into a fluorinated compound; or
a selective oxidation process selected from the following: oxidation of methanol to give formaldehyde or dimethoxymethane; oxidation of ethanol to give acetaldehyde or diethoxyethane; oxidation of ortho-xylene or naphthalene to give phthalic anhydride; oxidation of benzene, butene, butanol or butane to give maleic anhydride; oxidation of propylene to give acrolein; or oxidation of isobutene or tert-butanol to give methacrolein.
7. The process as claimed in claim 1 , wherein the reaction is of heterogeneous catalytic type and a catalyst is positioned in the reaction compartment in the form of solid particles.