IP Library Granted Patent US 9,738,849
Granted Patent B2
US 9,738,849 · App. 15/051,985 · Granted Aug 22, 2017

Lubricating composition containing an antiwear agent

Inventors: William R. S. Barton (Belper, GB); Mark C. Davies (Shanghai, CN); Michael R. Sutton (Belper, GB); Matthew D. Gieselman (Wickliffe, OH); Patrick E. Mosier (Bay Village, OH)
Assignee: The Lubrizol Corporation
C10M141/10C10M129/44C10M133/44C10M135/10C10M137/04C10M137/10C10M2207/028C10M2207/042C10M2207/124C10M2207/128C10M2207/24C10M2207/262C10M2207/281C10M2207/282C10M2207/283C10M2207/289C10M2215/02C10M2215/08C10M2215/082C10M2215/086C10M2215/223C10M2215/224C10M2215/28C10M2219/046C10M2219/089C10M2223/043C10M2223/045C10M2223/049C10N2230/06C10N2230/42C10N2230/43C10N2230/45C10N2240/10
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Quick Facts
Patent No.
US 9,738,849
App. No.
15/051,985
Granted
Aug 22, 2017
Kind
B2
Abstract

The invention provides a lubricating composition containing (a) an oil of lubricating viscosity, (b) a phosphite having at least one hydrocarbyl group that has 4 or more carbon atoms, and (c) a compound derived from a hydroxy-carboxylic acid. The invention further relates to the use of the lubricating composition in an internal combustion engine.

Claims (19)

1. A lubricating composition comprising

(a) an oil of lubricating viscosity,

(b) 0.5 wt % to 1.0 wt % of a phosphite having at least one hydrocarbyl group that has 4 or more carbon atoms, wherein the phosphite having at least one hydrocarbyl group with 4 or more is represented by the formula:

wherein at least one of R 3 , R 4 and R 5 is a hydrocarbyl group containing from at least 4 carbon atoms and the other may be hydrogen or a hydrocarbyl group, and wherein the phosphite has at least one hydrocarbyl group with 16 to 18 carbon atoms, and

(c) 0.1 wt % to 0.5 wt % of a compound derived from an ester of a hydroxy-carboxylic acid having linear or branched alkyl groups of 1 to 20 carbon atoms and selected from the group consisting of malic acid, citric acid, or mixtures thereof; and

(d) an overbased magnesium sulphonate detergent having a TBN of from 250 to 600 present in an amount from about 0.2 wt % to about 8 wt %;

wherein the lubricating composition is characterised as having (i) a sulphur content of 0.5 wt % or less, (ii) a phosphorus content of 0.1 wt % or less, and (iii) a sulphated ash content of 1.5 wt % or less.

2. The lubricating composition of claim 1 , wherein n and m both equal 2.

3. The lubricating composition of claim 1 , wherein both R 3 and R 4 are hydrocarbyl groups.

4. The lubricating composition of claim 1 further comprising a zinc dialkyldithiophosphate, or mixtures thereof, wherein the zinc dialkyldithiophosphate is present at 0.75 wt % to 1.5 wt % of the lubricating composition.

5. The lubricating composition of claim 1 further comprising at least one of an antiwear agent, a dispersant viscosity modifier, a friction modifier, a viscosity modifier, an antioxidant, an overbased detergent, or mixtures thereof.

6. A method of lubricating an internal combustion engine comprising supplying to the internal combustion engine the lubricating composition of claim 1 .

7. The method of claim 6 , wherein the internal combustion engine has surfaces of an aluminium alloy, or aluminium composite.

8. The method of claim 7 , wherein the aluminium alloy is a eutectic or hyper-eutectic aluminium alloy.

9. The method of claim 8 , wherein the aluminium alloy is derived from an aluminium silicate.

10. The method of claim 6 , wherein the internal combustion engine has surfaces of steel.

11. The method of claim 1 , wherein the compound is derived from malic acid.

12. The method of claim 1 , wherein the compound is derived from citric acid.

13. The method of claim 1 , wherein the lubricating composition is free of zinc dialkyldithiophosphate.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 12, 2017
From: BARTON, WILLIAM R.S.; DAVIES, MARK C.; SUTTON, MICHAEL R.; GIESELMAN, MATTHEW D.; MOSIER, PATRICK E.
To: THE LUBRIZOL CORPORATION
Reel/Frame 040957/0088 →
Continuity (3)
Continuation 13389517
Provisional Application 61234721 · Aug 18, 2009
Related Publication 20160168503A1 · Jun 16, 2016