Current collector, electrode, secondary battery and capacitor
Provided are a current collector which has an excellent high-rate property and exerts a sufficient safety function when employed in a secondary battery or a capacitor, as well as an electrode, a secondary battery or a capacitor in which said current collector is employed. According to the invention, a current collector is provided which comprises: metal foil; and a conductive layer with a film thickness of 0.1 μm to 10 μm formed on a surface of said metal foil. Here, said conductive layer includes a conductive material and a binder material. A melting point of said binder material is 80° C. to 150° C. Further, said binder material shows, in differential scanning calorimetry (DSC) in a range from room temperature to 200° C., one or more endothermic peaks in the heating-up process. In a case where said binder material shows two or more endothermic peaks, each difference between said peaks is 15° C. or more. Moreover, said binder material shows one or more exothermic peaks in the cooling-down process. In a case where said binder material shows only one exothermic peak, said exothermic peak falls within a range of 50 to 120° C., and a width at half maximum of said exothermic peak is 10° C. or less. On the other hand, in a case where said binder material shows two or more exothermic peaks, a maximum exothermic peak among said exothermic peaks falls within a range of 50 to 120° C., and a width at half maximum of said exothermic peak is 10° C. or less.
1. A current collector comprising:
metal foil; and
a conductive layer with a film thickness of 0.1 μm to 10 μm formed on a surface of the metal foil,
wherein the conductive layer includes a conductive material and a binder material,
a melting point of the binder material is 80° C. to 150° C., and
the binder material includes crystalline particles with a number average particle diameter of 10 μm or less, and shows, in differential scanning calorimetry (DSC) in a range from room temperature to 200° C., one or more endothermic peaks in a heating-up process and one or more exothermic peaks in a cooling-down process,
wherein in a case where two or more endothermic peaks are shown, each difference between the peaks is 15° C. or more,
in a case where only one exothermic peak is shown, the exothermic peak falls within a range of 50 to 120° C., and a width at half maximum of the exothermic peak is 10° C. or less, in a case where two or more exothermic peaks are shown, a largest exothermic peak among the exothermic peaks falls within the range of 50 to 120° C., and a width at half maximum of the exothermic peak is 10° C. or less, and
the crystalline particles include one or more kinds of crystalline particles selected from the group consisting of acid-modified polyethylene particles, acid-modified polypropylene particles, and ethylene-glycidyl methacrylate copolymer particles.
2. The current collector of claim 1 , wherein
the conductive material includes conductive particles.
3. The current collector of claim 2 , wherein the crystalline particles include one or more kinds of components having one or more kinds of hydrophilic groups selected from the group consisting of an epoxy group, a carboxyl group, and a carboxylic anhydride group.
4. The current collector of claim 2 , wherein the conductive particles include carbon black or carbon nanotube with an aspect ratio of 10 or more.
5. The current collector of claim 1 , wherein
the binder material includes a dispersion liquid of water in which crystalline particles are dispersed,
the conductive material includes conductive particles, and
the conductive layer is formed by applying a composition containing the binder material and the conductive material onto the surface of the metal foil.
6. The current collector of claim 5 , wherein the conductive layer is subjected to heat treatment at 100 to 150° C. after application of the composition.
7. The current collector of claim 1 , wherein
the conductive layer is formed on both front and back surfaces of the metal foil, and
in a resistance-temperature curve, for which resistance is measured on an object formed of a conductive rubber with a diameter of 1 cm which is sandwiched by a pair of the current collectors, which in turn are sandwiched by cylindrical electrodes made of brass with a diameter of 1 cm, while temperature is raised from room temperature to 200° C. at a raising rate of 10° C./ min. in a state where a load of 50 N is applied between the electrodes, Rmax/Rmin is 3 or more, where Rmax denotes a maximum resistance, Rmin denotes a minimum resistance between TO and Tmax, and Tmax denotes a temperature at which resistance is Rmax.
8. The current collector of claim 1 , wherein a maximum resistance Rbmax which is measured above 50° C. and at or below 200° C. on the current collector is three times a resistance R50 at 50° C. or more.
9. An electrode comprising:
the collector of claim 1 , and
an active material layer including an active material, formed on the conductive layer of the current collector.
10. A lithium secondary battery comprising the current collector of claim 1 .
11. A non-aqueous system lithium secondary battery comprising the current collector of claim 1 .
12. An electric double layer capacitor comprising the current collector of claim 1 .
13. A lithium-ion capacitor comprising the current collector of claim 1 .