Organic electroluminescent panel
The present invention provides an organic electroluminescent panel capable of increasing the luminous efficacy and decreasing the driving voltage of a top emission (TE) organic EL element. The organic electroluminescent panel of the present invention includes: a substrate; and an organic electroluminescent element provided on the substrate. The organic electroluminescent element is a top emission element that includes, in the order from the substrate side: an anode; a light-emitting layer; an electron transport layer; a first metal layer; a p-type oxide layer; and a transparent cathode. The top emission element is configured to emit light from the transparent cathode side. The light-emitting layer and the electron transport layer are each formed from an organic material. At least one of a mixture layer of a p-type oxide and a hole transport material and a second metal layer is provided between the electron transport layer and the transparent cathode.
1. An organic electroluminescent panel comprising:
a substrate; and
an organic electroluminescent element provided on the substrate,
the organic electroluminescent element being a top emission element that includes, in the order from the substrate side:
an anode;
a light-emitting layer;
an electron transport layer;
a first metal layer;
a p-type oxide layer; and
a transparent cathode, wherein
the top emission element being configured to emit light from the transparent cathode side,
the light-emitting layer and the electron transport layer each being formed from an organic material,
a mixture layer of a p-type oxide and a hole transport material being provided between the electron transport layer and the transparent cathode, and
the mixture layer is provided between the p-type oxide layer and the transparent cathode.
2. The organic electroluminescent panel according to claim 1 ,
wherein the absolute value of a work function of the first metal layer is smaller than the absolute value of a lowest unoccupied molecular orbital energy of the electron transport layer.
3. The organic electroluminescent panel according to claim 1 ,
wherein the second metal layer is provided between the p-type oxide layer and the transparent cathode.
4. The organic electroluminescent panel according to claim 1 ,
wherein the organic electroluminescent element comprises, in the order from the substrate side, a second light-emitting layer, a second electron transport layer, a second metal layer, and a second p-type oxide layer, between the anode and the light-emitting layer.
5. The organic electroluminescent panel according to claim 4 ,
wherein the absolute value of a work function of the second metal layer is smaller than the absolute value of a lowest unoccupied molecular orbital energy of the second electron transport layer.
6. The organic electroluminescent panel according to claim 1 ,
wherein the organic electroluminescent element includes a hole injection layer between the anode and the light-emitting layer, and the mixture layer is made of the same material as a material of the hole injection layer.
7. The organic electroluminescent panel according to claim 1 ,
wherein the mixture layer is a p-doped layer formed by co-deposition of an organic hole injection material and the p-type oxide.
8. The organic electroluminescent panel according to claim 7 ,
wherein the organic hole injection material is α-NPD.
9. The organic electroluminescent panel according to claim 7 ,
wherein the p-type oxide is molybdenum trioxide.
10. The organic electroluminescent panel according to claim 1 ,
wherein the mixture layer is provided between the first metal layer and the p-type oxide layer.
11. The organic electroluminescent panel according to claim 1 ,
wherein the mixture layer is provided between the electron transport layer and the first metal layer.
12. The organic electroluminescent panel according to claim 7 ,
wherein an amount of the p-type oxide in the mixture layer is 10 to 50% by weight.
13. The organic electroluminescent panel according to claim 7 ,
wherein an amount of the p-type oxide in the mixture layer is 15 to 25% by weight.