Iron chalcogenide nanocomposite and method for preparing same
The present invention relates to an iron chalcogenide nanocomposite with photoluminescent properties. The present invention also relates to a method for preparing the iron chalcogenide nanocomposite. The method includes (a) dissolving a Fe precursor in an organic solvent to form a Fe solution, (b) dissolving a chalcogen powder or a chalcogen precursor in an organic solvent to form a chalcogen solution, (c) dropwise injecting the Fe solution into the chalcogen solution to prepare a mixture solution in which an iron chalcogenide is formed, and (d) purifying the iron chalcogenide from the mixture solution.
1. A method for preparing an iron chalcogenide nanocomposite, comprising
(a) dissolving a Fe precursor in an organic solvent to form a Fe solution,
(b) dissolving a chalcogen powder or a chalcogen precursor in an organic solvent to form a chalcogen solution,
(c) dropwise injecting the Fe solution into the chalcogen solution to prepare a mixture solution in which an iron chalcogenide is formed, and
(d) purifying the iron chalcogenide from the mixture solution.
2. The method according to claim 1 , wherein, in step (a) or (b), the organic solvent is heated to 100 to 140° C.
3. The method according to claim 1 , wherein the organic solvent used in step (a) or (b) is selected from the group consisting of ether-based compounds (CnOCn, Cn: hydrocarbon, 4≦n≦30), hydrocarbons (C n H 2n+2 , 7≦n≦30), unsaturated hydrocarbons (C n H 2n , 7≦n≦30), and organic acids (C n COOH, C n : hydrocarbon, 5≦n≦30).
4. The method according to claim 3 , wherein the ether-based compounds are selected from the group consisting of trioctylphosphine oxide (TOPO), alkylphosphines, octyl ether, benzyl ether, and phenyl ether.
5. The method according to claim 3 , wherein the hydrocarbons are selected from the group consisting of hexadecane, heptadecane, and octadecane.
6. The method according to claim 3 , wherein the unsaturated hydrocarbons are selected from the group consisting of octene, heptadecene, and octadecene.
7. The method according to claim 3 , wherein the organic acids are selected from the group consisting of oleic acid, lauric acid, stearic acid, mysteric acid, and hexadecanoic acid.
8. The method according to claim 3 , wherein, in step (c), the Fe solution is injected dropwise into the chalcogen solution, followed by heating to 250 to 400° C. to prepare a mixture solution in which an iron chalcogenide is formed.
9. The method according to claim 3 , wherein, in step (c), a surfactant is added to and mixed with the mixed solution.
10. The method according to claim 9 , wherein the surfactant is an organic acid selected from the group consisting of oleic acid, lauric acid, stearic acid, mysteric acid, and hexadecanoic acid or is a mixture of these organic acids.
11. The method according to claim 3 , wherein the Fe precursor and the chalcogen precursor are used in a molar ratio of 1:1-2.
12. The method according to claim 3 , wherein the chalcogen is S, Se or Te.
13. The method according to claim 12 , wherein the iron chalcogenide is FeSe or FeSe 2 .