IP Library Granted Patent US 9,761,734
Granted Patent B2
US 9,761,734 · App. 15/174,197 · Granted Sep 12, 2017

Semiconductor device

Inventors: Noritaka Ishihara (Koza, JP); Masashi Oota (Atsugi, JP); Masashi Tsubuku (Atsugi, JP); Masami Jintyou (Shimotsuga, JP); Yukinori Shima (Tatebayashi, JP); Junichi Koezuka (Tochigi, JP); Yasuharu Hosaka (Tochigi, JP); Shunpei Yamazaki (Setagaya, JP)
Assignee: Semiconductor Energy Laboratory Co., Ltd.
H01L29/7869H01L27/1225H01L29/41733H01L29/45H01L29/78648H01L29/78693H01L29/78696
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Quick Facts
Patent No.
US 9,761,734
App. No.
15/174,197
Granted
Sep 12, 2017
Kind
B2
Abstract

Defects in an oxide semiconductor film are reduced in a semiconductor device including the oxide semiconductor film. The electrical characteristics of a semiconductor device including an oxide semiconductor film are improved. The reliability of a semiconductor device including an oxide semiconductor film is improved. A semiconductor device including an oxide semiconductor layer; a metal oxide layer in contact with the oxide semiconductor layer, the metal oxide layer including an In-M oxide (M is Ti, Ga, Y, Zr, La, Ce, Nd, or Hf); and a conductive layer in contact with the metal oxide layer, the conductive layer including copper, aluminum, gold, or silver is provided. In the semiconductor device, y/(x+y) is greater than or equal to 0.75 and less than 1 where the atomic ratio of In to M included in the metal oxide layer is In:M=x:y.

Claims (47)

1. A semiconductor device comprising:

a transistor that comprises:

a gate electrode;

a gate insulating layer over the gate electrode;

an oxide semiconductor layer over and in contact with the gate insulating layer, the oxide semiconductor layer comprising In, Ga and Zn;

an oxide layer over the oxide semiconductor layer, the oxide layer comprising In and Ga;

a first conductive layer in contact with a top surface of the oxide layer, a side surface of the oxide layer, and a side surface of the oxide semiconductor layer; and

a second conductive layer in contact with a top surface of the oxide layer, a side surface of the oxide layer, and a side surface of the oxide semiconductor layer,

wherein y1/x1 is greater than or equal to 1 and less than 3 where an atomic ratio of In to Ga included in the oxide semiconductor layer is In:Ga=x1:y1, and

wherein y2/(x2+y2) is greater than or equal to 0.80 and less than 0.90 where an atomic ratio of In to Ga included in the oxide layer is In:Ga=x2:y2.

2. The oxide layer according to claim 1 , wherein the oxide layer does not comprise Zn.

3. The semiconductor device according to claim 1 , wherein each of the first conductive layer and the second conductive layer comprises a stack of a titanium layer and a copper layer over the titanium layer.

4. The semiconductor device according to claim 1 , wherein a conductivity of the oxide layer is lower than a conductivity of the oxide semiconductor layer.

5. The semiconductor device according to claim 1 , wherein off-state current of the transistor is less than or equal to 1×10 −13 A at a voltage between a source of the transistor and a drain of the transistor is 10 V.

6. A semiconductor device comprising:

an oxide semiconductor layer comprising a channel formation region;

an oxide layer over the oxide semiconductor layer, the oxide layer comprising In and Ga; and

a gate electrode overlapping with the oxide semiconductor layer and the oxide layer,

wherein y/(x+y) is greater than or equal to 0.80 and less than 0.90 where an atomic ratio of In to Ga included in the oxide layer is In:Ga=x:y.

7. The semiconductor device according to claim 6 , wherein the oxide layer does not comprise Zn.

8. The semiconductor device according to claim 6 , wherein the oxide semiconductor layer comprises In, Ga and Zn.

9. The semiconductor device according to claim 6 , wherein a conductivity of the oxide layer is lower than a conductivity of the oxide semiconductor layer.

10. A semiconductor device comprising:

an oxide semiconductor layer comprising a channel formation region;

an oxide layer over the oxide semiconductor layer, the oxide layer comprising In and Ga; and

an electrode over the oxide layer and electrically connected to the oxide semiconductor layer,

wherein y/(x+y) is greater than or equal to 0.80 and less than 0.90 where an atomic ratio of In to Ga included in the oxide layer is In:Ga=x:y,

wherein the oxide layer is located between the oxide semiconductor layer and the electrode, and

wherein the electrode comprise Cu.

11. The semiconductor device according to claim 10 , wherein the oxide layer does not comprise Zn.

12. The semiconductor device according to claim 10 , wherein the oxide semiconductor layer comprises In, Ga and Zn.

13. The semiconductor device according to claim 10 , wherein a conductivity of the oxide layer is lower than a conductivity of the oxide semiconductor layer.

14. A semiconductor device comprising:

a transistor that comprises:

a gate electrode;

a gate insulating layer over the gate electrode;

an oxide semiconductor layer over and in contact with the gate insulating layer, the oxide semiconductor layer comprising In, Ga and Zn;

an oxide layer over the oxide semiconductor layer, the oxide layer comprising In and Ga;

a first conductive layer in contact with a top surface of the oxide layer, a side surface of the oxide layer, and a side surface of the oxide semiconductor layer; and

a second conductive layer in contact with a top surface of the oxide layer, a side surface of the oxide layer, and a side surface of the oxide semiconductor layer,

wherein y1/x1 is greater than or equal to 1 and less than 3 where an atomic ratio of In to Ga included in the oxide semiconductor layer is In:Ga=x1:y1,

wherein y2/(x2+y2) is greater than or equal to 0.80 and less than 0.90 where an atomic ratio of In to Ga included in the oxide layer is In:Ga=x2:y2, and

wherein a thickness of the oxide layer is greater than or equal to 10 nm and less than or equal to 100 nm.

15. The semiconductor device according to claim 14 , wherein the oxide layer does not comprise Zn.

16. The semiconductor device according to claim 14 , wherein each of the first conductive layer and the second conductive layer comprises a stack of a titanium layer and a copper layer over the titanium layer.

17. The semiconductor device according to claim 14 , wherein a conductivity of the oxide layer is lower than a conductivity of the oxide semiconductor layer.

18. The semiconductor device according to claim 14 , wherein off-state current of the transistor is less than or equal to 1×10 −13 A at a voltage between a source of the transistor and a drain of the transistor is 10 V.

Priority Claims (1)
JP 2013-196333 · Sep 23, 2013 · national
Continuity (2)
Continuation 14486089 · Sep 15, 2014
Related Publication 20160284860A1 · Sep 29, 2016