IP Library › Granted Patent US 9,786,744
Granted Patent B2
US 9,786,744 · App. 15/341,590 · Granted Oct 10, 2017

P-doping of group-III-nitride buffer layer structure on a heterosubstrate

Inventors: Stephan Lutgen (Dresden, DE); Saad Murad (Freital, DE); Ashay Chitnis (Dresden, DE)
Assignee: AZURSPACE Solar Power GmbH
H01L29/205H01L21/0251H01L21/0254H01L21/02378H01L21/02381H01L21/02458H01L21/02505H01L21/02507H01L21/02579H01L29/1075H01L29/151H01L29/2003H01L29/207H01L29/36H01L29/778H01L29/7783H01L29/872H01L33/0025
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Quick Facts
Patent No.
US 9,786,744
App. No.
15/341,590
Granted
Oct 10, 2017
Kind
B2
Abstract

An epitaxial group-ill-nitride buffer-layer structure is provided on a heterosubstrate, wherein the buffer-layer structure has at least one stress-management layer sequence including an interlayer structure arranged between and adjacent to a first and a second group-ill-nitride layer, wherein the inter layer structure comprises a group-ill-nitride interlayer material having a larger band gap than the materials of the first and second group-ill-nitride layers, and wherein a p-type-dopant-concentration profile drops, starting from at least 1×1018 cm-3, by at least a factor of two in transition from the interlayer structure to the first and second group-ill-nitride layers.

Claims (29)

1. An epitaxial group-III-nitride buffer-layer structure on a silicon, wherein the buffer-layer structure comprises at least one stress management layer sequence including an interlayer structure arranged between and adjacent to a first group-III-nitride layer and a second group-III-nitride layer,

wherein the interlayer structure comprises a group-III-nitride interlayer material having a larger band gap than the materials of the first and second group-III-nitride layers,

wherein a p-type-dopant-concentration profile drops, starting from at least 1×10 18 cm −3 , by at least a factor of two in transition from the interlayer structure to the first and second group-III-nitride layers,

wherein a thickness of the first group-III-nitride layer is between 300 nm and 2000 nm, and

wherein a thickness of the second group-III-nitride layer is between 300 nm and 1500 nm.

2. The buffer-layer structure according to claim 1 , wherein the interlayer structure comprises a single layer and has a thickness between 10 nm and 50 nm.

3. The buffer-layer structure according to claim 1 , wherein the interlayer structure is made of AlGaN, or wherein the interlayer structure uses AlN, or AlInN, or AlInGaN.

4. The buffer-layer structure according to claim 1 , wherein the stress-management layer sequence is made of GaN—AlGaN—GaN.

5. The buffer-layer structure according to claim 1 , wherein the p-type-dopant-concentration profile drops in transition from the interlayer structure to the first and second group-III-nitride layers by at least one order of magnitude or by at least two orders of magnitude, or wherein a carbon concentration in the interlayer structure is three orders of magnitude higher than in the first and second group-III-nitride layers.

6. The buffer-layer structure according to claim 1 , wherein the interlayer structure comprises three different layers, a first group-III-nitride interlayer, a second group-III-nitride interlayer and a third group-III-nitride interlayer that have a thickness between 20 nm and 200 nm.

7. The buffer-layer structure according to claim 6 , wherein the second and third group-III-nitride interlayers comprise a constant aluminum content.

8. The buffer-layer structure according to claim 6 , wherein the second and third group-III-nitride interlayers and the first and second group-III-nitride layers are made of GaN, and wherein the first group-III-nitride interlayer is formed of AlGaN.

9. The buffer-layer structure according to claim 6 , wherein the second and third group-III-nitride interlayers comprise a gradient in the aluminum content.

10. The buffer-layer structure according to claim 9 , wherein the second and third group-III-nitride interlayers and the first and second group-III-nitride layers are made of GaN, and wherein an aluminum content of the first group-III-nitride interlayer increases from 10% at the interface to the second group-III-nitride interlayer to 70% at the interface to the third group-III-nitride interlayer.

11. The buffer-layer structure according to claim 10 , wherein a hole concentration caused by p-doping is constant within an entirety of the interlayer structure, and in the first, second, and third group-III-nitride interlayers.

12. The buffer-layer structure according to claim 10 , wherein the hole concentration caused by p-doping is 1×10 18 cm −3 within the entirety of the interlayer structure, and in the first, second, and third group-III-nitride interlayers.

13. The buffer-layer structure according to claim 9 , wherein a hole concentration caused by p-doping for the second and third group-III-nitride interlayers is higher than a hole concentration of the first group-III-nitride interlayer.

14. The buffer-layer structure according to claim 9 , wherein the first group-III-nitride interlayer is unintentionally doped.

15. The buffer-layer structure according to claim 9 , wherein a hole concentration caused by p-doping 5×10 18 cm −3 in the second and third group-III-nitride interlayers.

16. The buffer-layer structure according to claim 1 , wherein the first and second group-III-nitride layers are only unintentionally p-doped.

17. The buffer-layer structure of claim 1 , wherein the p-type dopant is carbon or magnesium, or a combination of carbon and magnesium.

18. The buffer layer structure according to claim 1 , further comprising at least two stress management layer sequences, wherein a second stress management layer sequence arranged at a larger distance from the substrate than a first stress management layer sequence has a second interlayer structure.

19. The buffer layer structure according to claim 18 , wherein the second interlayer structure differs from the first interlayer structure in at least one of the following: a layer thickness of at least one of the interlayers of the interlayer structure, a p-type dopant concentration in at least one of the interlayers of the interlayer structure, a material composition of at least one of the interlayers of the interlayer structure, and/or a number of interlayers in the interlayer structure.

20. The buffer layer structure according to claim 1 , wherein an additional group-III-nitride layer is deposited on top of the buffer-layer structure, wherein the additional group-III-nitride layer has a graded p-type-dopant-concentration profile, wherein the p-type dopant concentration is higher in a first section of the additional group-III-nitride layer adjacent to the buffer-layer structure than in a second section of the additional group-III-nitride layer further away from the buffer-layer structure.

21. The buffer layer structure according to claim 1 , further comprising a buffer stack deposited between a heterosubstrate and the at least one stress management layer sequence, the buffer stack comprising:

a compositionally graded AlGaN buffer layer having a Ga fraction increasing with increasing distance from the heterosubstrate, or

a superlattice formed by a stack of alternating group-III-nitride layers of two kinds,

wherein the buffer stack has a p-type-dopant concentration of at least 1×10 17 cm −3 .

22. A group-III-nitride device, a FET, a normally-on or a normally-off HEMT or MIS-HEMT, a Schottky diode, a PIN diode, or a LED comprising an epitaxial group-III-nitride buffer layer structure on a heterosubstrate according to claim 1 .

Priority Claims (1)
EP 13155540 · Feb 15, 2013 · regional
Continuity (3)
Continuation 14828148 · Aug 17, 2015
Continuation PCTEP2014052957 · Feb 14, 2014
Related Publication 20170077242A1 · Mar 16, 2017