Nanofiber-based heterojunction approach for high photoconductivity on organic materials
The present disclosure provides methods and compositions for an organic nanofiber-based heterojunction material, comprising nano fibers of an acceptor molecule, the nano fibers coated with a donor molecule, where the acceptor molecule contains a group and the donor molecule contains a companion group, wherein the group and companion group enables strong binding between the acceptor molecule and donor molecule, the strong binding providing for efficient forward electron transfer between the acceptor molecule and donor molecule, and wherein the group and companion group minimize charge carrier recombination between the acceptor molecule and the donor molecule.
1. An organic nanofiber-based heterojunction material, comprising nanofibers of an acceptor molecule, the nanofibers coated with a donor molecule; wherein the acceptor molecule contains a group and the donor molecule contains a companion group;
wherein the group and companion group enables strong binding between the acceptor molecule and donor molecule, the strong binding providing for efficient collection of free charge carriers between the acceptor molecule and donor molecule, and wherein the group and companion group minimize charge carrier recombination between the acceptor molecule and the donor molecule.
2. The organic nanofiber-based heterojunction material of claim 1 , wherein the donor molecule is a carbazole.
3. The organic nanofiber-based heterojunction material of claim 1 , wherein the donor molecule is selected from the group consisting of
where R1, R2, and R3 individually represent the companion groups and are independently selected from the group consisting of H, branched alkyl, linear alkyl, substituted alkyl, unsubstituted alkyl, functionalized alkyls, and combinations thereof.
4. The organic nanofiber-based heterojunction material of claim 3 , wherein the R1, R2, and R3 companion groups are independently selected from the group consisting of C 2 -C 16 alkyls, C 2 -C 16 alkyl ethers, C 3 -C 20 branched alkyls.
5. The organic nanofiber-based heterojunction material of claim 3 , wherein the R1, R2, and R3 companion groups are independently C 2 -C 16 alkyls.
6. The organic nanofiber-based heterojunction material of claim 5 , wherein the donor molecule is
7. The organic nanofiber-based heterojunction material of claim 6 , wherein at least one of the R1, R2, and R3 companion groups is different.
8. The organic nanofiber-based heterojunction material of claim 6 , wherein the R1, R2, and R3 companion groups are the same.
9. The organic nanofiber-based heterojunction material of claim 1 , wherein the acceptor molecule is
where R4 and R5 are the groups and are independently selected from the group consisting of H, branched alkyl, linear alkyl, substituted alkyl, unsubstituted alkyl, functionalized alkyl, and combinations thereof.
10. The organic nanofiber-based heterojunction material of claim 9 , wherein the R4 and R5 groups are independently selected from the group consisting of C 2 -C 16 alkyls, C 2 -C 16 alkyl ethers, C 3 -C 20 branched alkyls.
11. The organic nanofiber-based heterojunction material of claim 9 , wherein the R4 and R5 groups are independently C 2 -C 16 alkyls.
12. The organic nanofiber-based heterojunction material of claim 1 , wherein the nanofibers are 1 μm to 10 μm in length and 10 nm to 100 nm in width.
13. The organic nanofiber-based heterojunction material of claim 1 , wherein the efficient collection of free charge carriers is measured as a photocurrent generation quantum efficiency of the material of at least 8%.
14. The organic nanofiber-based heterojunction material of claim 1 , wherein a photoresponse of the organic nanofiber-based heterojunction material is at the range of about 200 ms.
15. The organic nanofiber-based heterojunction material of claim 1 , wherein organic nanofiber-based heterojunction material has a fluorescence quenching of 40-90%.
16. The organic nanofiber-based heterojunction material of claim 1 , wherein the nanofibers have a wt % ratio of donor molecule to acceptor molecule of 1:20 to 20:1.