Carbon dioxide absorbent based on amine having nitrile functional group, and carbon dioxide absorption method and separation method using same
The present invention relates to a method for using, as a carbon dioxide absorbent, a secondary amine having a nitrile group, that is, a 3-(alkylamino)propionitrile compound. The absorbent based on the 3-(alkylamino)propionitrile compound and the carbon dioxide absorption method and separation method using same, according to the present invention, not only have an excellent carbon dioxide absorption capacity and a rapid carbon dioxide absorption rate, but also allow absorbent regeneration even at a considerably low temperature compared with a conventional alkanolamine-based absorbent and thus can significantly reduce the entire energy consumption required for an absorption process, and can also prevent recovered carbon dioxide from being contaminated with moisture and absorbent vapor, owing to the low regeneration temperature.
1. A carbon dioxide (CO 2 ) absorbent based on an amine having a nitrile functional group, wherein the carbon dioxide absorbent consists essentially of a mixture of a 3-(alkylamino)propionitrile compound represented by Formula 3 and a secondary alkanolamine represented by Formula 4,
R 1 —NH—CH 2 —CH 2 —C≡N Formula 3,
wherein R 1 represents a C1 to C6 alkyl group or a cycloalkyl group, R 2 represents a C1 to C6 alkyl group, and R 3 represents hydrogen or a methyl group.
2. The carbon dioxide absorbent of claim 1 , wherein an amount of the secondary alkanolamine is 20 to 150 parts by weight with respect to 100 parts by weight of the 3-(alkylamino)propionitrile compound used as a main absorbent.
3. A method of absorbing carbon dioxide, the method comprising absorbing carbon dioxide by using the carbon dioxide absorbent of claim 1 , the carbon dioxide absorbent being dissolved in water or in an organic solvent.
4. The method of claim 3 , wherein the organic solvent is at least one selected from the group consisting of a C1 to C6 alcohol, an amide compound, a ketone compound, dimethyl sulfoxide (DMSO), N-methylpyrrolidinone (NMP), and sulfolane.
5. The method of claim 3 , wherein an amount of the mixture of the 3-(alkylamino)propionitrile compound and the secondary alkanolamine is 10 to 150 parts by weight with respect to 100 parts by weight of the solvent.
6. A method of separating carbon dioxide, the method comprising: a first step of absorbing carbon dioxide from a gas mixture containing carbon dioxide by using the carbon dioxide absorbent of claim 1 ; and a second step of separating carbon dioxide absorbed by the carbon dioxide absorbent.
7. The method of claim 6 , wherein a temperature of the absorption in the first step is 20° C. to 60° C.
8. The method of claim 6 , wherein a pressure of the absorption in the first step is normal pressure to 30 atmospheres.
9. The method of claim 6 , wherein a temperature of the separation in the second step is 70° C. to 120° C.
10. The method of claim 6 , wherein a pressure of the separation in the second step is normal pressure.
11. The method of claim 6 , wherein a temperature of the absorption in the first step is 20° C. to 60° C., wherein a pressure of the absorption in the first step is normal pressure to 30 atmospheres, wherein a temperature of the separation in the second step is 70° C. to 120° C., and wherein a pressure of the separation in the second step is normal pressure.