IP Library Granted Patent US 9,802,163
Granted Patent B2
US 9,802,163 · App. 14/621,795 · Granted Oct 31, 2017

Electrically conducting reverse osmosis membranes

Inventors: David Jassby (Riverside, CA); Mark Wiesner (Raleigh, NC); Charles-Francois de Lannnoy (Hamilton, CA)
Assignees: The Regents of the University of California; Duke University
B01D71/021B01D65/08B01D67/0079B01D69/02B01D69/148B01D71/56C02F1/441B01D61/025B01D2325/26C02F2303/20
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Quick Facts
Patent No.
US 9,802,163
App. No.
14/621,795
Granted
Oct 31, 2017
Kind
B2
Abstract

The disclosure provides composite membranes for use in water purification and filtration.

Claims (12)

1. An electrically conductive composite membrane comprising a polymer support, a functionalized carbon nanotube (CNT) layer on the polymer support, and a polyamide-CNT layer on the CNT layer, wherein the polyamide-CNT layer comprises CNTs incorporated within a polyamide matrix, and wherein the electrically conductive composite membrane has electric conductivity of about 400 S/m.

2. The electrically conductive membrane of claim 1 , wherein the CNTs form ester bonds with trimesoyl choloride.

3. The electrically conductive composite membrane of claim 1 formed by:

pressure depositing a solution of functionalized carbon nanotubes onto a polymer membrane support to form a CNT-membrane composite; and

drying the composite.

4. The electrically conductive composite membrane of claim 3 , wherein the functionalized carbon nanotubes are prepared by placing functionalized carbon nanotubes (CNTs) in powder form in deionized water at a concentration of about 0.05 to about 0.15 mg/ml together with a surfactant and sonicating suspension to form a solution.

5. The electrically conductive composite membrane of claim 4 , wherein the surfactant is sodium dodecylbenzenesulfonate.

6. The electrically conductive composite membrane of claim 4 , wherein the solution is centrifuged to remove clumps and debris.

7. The electrically conductive composite membrane of claim 3 , wherein the pressure depositing is performed at a pressure of about 50 psi or greater on a membrane support.

8. The electrically conductive composite of claim 1 or 3 , wherein the functionalized carbon nanotubes are functionalized with COOH, OH, and/or NH 2 functional groups.

9. The electrically conductive composite of claim 1 or 3 , wherein the carbon nanotubes are single-walled, multi-walled, or double-walled carbon nanotubes.

10. The electrically conductive composite of claim 1 or 3 , wherein the membrane support comprises a polyethersulfone or polysulfone.

Assignments (3)
CONFIRMATORY LICENSE Recorded Oct 23, 2019
From: DUKE UNIVERSITY
To: NATIONAL SCIENCE FOUNDATION
Reel/Frame 050809/0348 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 14, 2017
From: WIESNER, MARK; DE LANNOY, CHARLES-FRANCOIS
To: DUKE UNIVERSITY
Reel/Frame 043593/0488 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 14, 2017
From: JASSBY, DAVID
To: THE REGENTS OF THE UNIVERSITY OF CALIFORNIA
Reel/Frame 043593/0659 →
Continuity (2)
Provisional Application 61939613 · Feb 13, 2014
Related Publication 20150224450A1 · Aug 13, 2015