Method for recycling a plastic
View Patent ↗A method of recycling a plastic includes decomposing the plastic in the presence of a catalyst to form hydrocarbons. The catalyst includes a porous support having an exterior surface and defining at least one pore therein. The catalyst also includes a depolymerization catalyst component disposed on the exterior surface of the porous support for depolymerizing the plastic. The depolymerization catalyst component includes a Ziegler-Natta catalyst, a Group IIA oxide catalyst, or a combination thereof. The catalyst further includes a reducing catalyst component disposed in the at least one pore.
1. A method of recycling a plastic chosen from polyethylene, polypropylene, polystyrene, and combinations thereof, said method comprising: decomposing the plastic in the presence of a catalyst to form hydrocarbons and reducing the hydrocarbons in the presence of a reducing agent that is different from the catalyst,
wherein the catalyst comprises a porous support having an exterior surface and at least one pore therein, a depolymerization catalyst component comprising a metallocene catalyst disposed on the exterior surface of the porous support, and a reducing catalyst component disposed in the at least one pore;
wherein the exterior surface of the porous support comprises less than 10 parts by weight of the reducing catalyst component based on 100 parts by weight of the depolymerization catalyst component as determined using Energy Dispersive X-Ray Spectroscopy (EDS),
wherein the reducing catalyst component comprises a transition metal selected from the group of iron, nickel, palladium, platinum, and combinations thereof, and
wherein the at least one pore in the porous support has an average pore size of 10 Angstroms.
2. The method of claim 1 wherein the metallocene catalyst comprises zirconium.
3. The method of claim 2 wherein the metallocene catalyst is bis(cyclopentadienyl)zirconium(IV).
4. The method of claim 1 wherein the porous support is a molecular sieve.
5. The method of claim 1 wherein the plastic is decomposed in the presence of from 0.1 part of the catalyst per one million parts of the plastic to 100 parts of the catalyst per 100 parts of the plastic.
6. The method of claim 1 wherein the decomposing occurs at a temperature of from 400° C. to 600° C.
7. The method of claim 1 further comprising purifying the hydrocarbon to form purified hydrocarbons.
8. The method of claim 7 wherein the purified hydrocarbons comprise gasoline, diesel fuel, or a combination thereof.
9. The method of claim 1 wherein the polyethylene is selected from the group of low density polyethylene, linear low density polyethylene, high density polyethylene, and combinations thereof.
10. The method of claim 1 wherein the plastic consists essentially of polyethylene, polypropylene, and combinations thereof.
11. The method of claim 10 wherein the polyethylene is selected from the group of low density polyethylene, linear low density polyethylene, high density polyethylene, and combinations thereof.
12. The method of claim 1 wherein the hydrocarbons have from 4 to 40 carbon atoms.
13. The method of claim 1 wherein the hydrocarbons have from 5 to 25 carbon atoms.
14. The method of claim 1 wherein the reducing agent is hydrogen gas.
15. The method of claim 1 wherein the plastic is decompressed in the presence of from 0.1 part of the catalyst per one million parts of the plastic to 100 parts of the catalyst per 100 parts of the plastic, wherein the depolymerization catalyst component is bis(cyclopentadienyl)zirconium(IV), wherein the reducing catalyst component comprises palladium, wherein the reducing agent is hydrogen gas, and wherein the porous support is a 13X molecular sieve.