IP Library Granted Patent US 9,802,391
Granted Patent B2
US 9,802,391 · App. 15/094,148 · Granted Oct 31, 2017

Non-black rubber membranes

Inventors: Hao Wang (Carmel, IN); James A. Davis (Summerfield, FL); William F. Barham, Jr. (Prescott, AZ)
Assignee: Firestone Building Products Co., LLC
B32B25/14B29C43/24B29C43/305B29C65/70B32B5/028B32B25/02B32B25/042B32B25/10C08K3/36C08K5/548E04D5/06E04D5/08E04D5/10B29D7/01B29K2009/00B29K2483/00B29K2505/00B29K2509/00B32B2250/248B32B2264/10B32B2264/102B32B2307/3065B32B2307/536B32B2307/54B32B2307/5825B32B2307/726B32B2307/732B32B2307/734B32B2419/06Y10T428/31667Y10T442/10
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Quick Facts
Patent No.
US 9,802,391
App. No.
15/094,148
Granted
Oct 31, 2017
Kind
B2
Abstract

A roofing membrane comprising an olefinic rubber; and from about 20 to about 250 parts by weight of a silica filler per 100 parts by weight rubber; wherein the silica filler is chemically coupled to the olefinic rubber; and wherein the roofing membrane is non-black.

Claims (12)

1. A roofing membrane comprising:

(i) a non-black element including silica dispersed within a crosslinked network of ethylene-propylene-diene rubber, where the silica is chemically coupled to the crosslinked network through a reaction with a coupling agent defined by the formula:

where R 8 is a divalent organic group or a bond, R 9 is a halogen atom or an alkoxy group, and each R 10 is independently a halogen, an alkoxy group, or a monovalent organic group, and where R 11 is a blocking group.

2. The membrane of claim 1 , where the non-black element includes at least 15 and less than 250 parts by weight silica per 100 parts by weight rubber.

3. The membrane of claim 1 , where the non-black element includes at least 20 and less than 200 parts by weight silica per 100 parts by weight rubber.

4. The membrane of claim 1 , where the non-black element further includes titanium dioxide.

5. The membrane of claim 4 , where the non-black element includes at least 20 and less than 90 parts by weight titanium dioxide per 100 parts by weight rubber.

6. The membrane of claim 1 , where the non-black element further includes a processing oil.

7. The membrane of claim 6 , where the non-black element includes at least 30 and less than 120 parts by weight processing oil per 100 parts by weight rubber.

8. The membrane of claim 7 , where the processing oil is a white oil.

9. The membrane of claim 6 , where the processing oil has a sulfur content of less than 0.5 weight percent and an unsaturation level of less than 3%.

10. The membrane of claim 1 , where the coupling agent is a thioester, a thiophosphinate, a thiophosphate, or a thiosulphonate.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 28, 2025
From: HOLCIM TECHNOLOGY LTD
To: AMRIZE TECHNOLOGY SWITZERLAND LLC
Reel/Frame 073030/0406 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 26, 2022
From: FIRESTONE BUILDING PRODUCTS COMPANY, LLC
To: HOLCIM TECHNOLOGY LTD
Reel/Frame 060920/0869 →
Continuity (5)
Continuation 14446213 · Jul 29, 2014
Division 13287417 · Nov 2, 2011
Division 12389145 · Feb 19, 2009
Provisional Application 61029777 · Feb 19, 2008
Related Publication 20160221309A1 · Aug 4, 2016