Method of preparing fiber-reinforced polymer composites and fiber-reinforced polymer composites prepared thereof
A method of preparing a fiber-reinforced polymer composite is provided. The method includes (a) providing a swollen clay material; (b) chemically modifying a surface of the swollen clay material with an organosilane to form a silane-modified clay material; (c) intercalating the silane-modified clay material with a binder to form an intercalated clay material; and (d) melt compounding the intercalated clay material with a mixture comprising a polymer and fiber to form the fiber-reinforced polymer composite. A fiber-reinforced polymer composite is also provided.
1. A method of preparing a fiber-reinforced polymer composite, the method comprising
a) providing a swollen clay material comprising a clay material and an aqueous medium dispersed between layers of the clay material;
b) chemically modifying a surface of the swollen clay material with an organosilane to form a silane-modified clay material;
c) intercalating the silane-modified clay material with a binder to form an intercalated clay material; and
d) melt compounding the intercalated clay material with a mixture comprising a polyamide polymer and discrete, elongated pieces of fiber, thereby dispersing the intercalated clay material along with the fiber in the polyamide polymer, to form the fiber-reinforced polymer composite.
2. The method according to claim 1 , wherein providing a swollen clay material comprises dispersing and swelling a clay material in an aqueous medium comprising acetic acid.
3. The method according to claim 1 , wherein the swollen clay material comprises montmorillonite clay.
4. The method according to claim 1 , wherein chemically modifying a surface of the swollen clay material with an organosilane is carried out in acetone.
5. The method according to claim 1 , wherein the organosilane comprises (3-glycidyloxypropyl)trimethoxy silane.
6. The method according to claim 1 , wherein the binder comprises an epoxy resin.
7. The method according to claim 1 , further comprising drying the intercalated clay material before melt compounding operation d), wherein the drying is carried out by spray drying or freeze drying.
8. The method according to claim 1 , wherein melt compounding the intercalated clay material is carried out at a temperature in the range of 200° C. To 300° C.
9. The method according to claim 1 , wherein melt compounding the intercalated clay material is carried out in a twin screw extruder.
10. The method according to claim 9 , wherein length-to-diameter ratio of the twin screw extruder is in the range of about 25 to about 27.
11. The method according to claim 9 , wherein screw rotation of the twin screw extruder is in the range of about 100 revolutions per minute to about 200 revolutions per minute.
12. The method according to claim 1 , wherein the fiber comprises glass.