Conductive ink
Provided is a conductive ink including a conductive material and at least one benzoxazine-based compound. The conductive ink of the present invention can be easily formed into a thin film, is highly conductive after sintering, and has superior adhesion to various substrates. In addition, the use of the conductive ink according to the present invention facilitates the formation of a glossy, mirror-like metal thin film with high reflectance.
1. A conductive ink comprising a metal particle or a metal precursor and at least one benzoxazine-based compound selected from structures represented by the following Formulas 1-1 to 1-4:
wherein R 1 , R 2 , R 3 , R 4 , and R 5 are each independently hydrogen, halogen, amino, nitro, cyano, hydroxyl, carboxyl, substituted or unsubstituted C 1 -C 30 alkyl, substituted or unsubstituted C 3 -C 30 cycloalkyl, substituted or unsubstituted C 6 -C 30 aryl, substituted or unsubstituted C 6 -C 30 aralkyl, substituted or unsubstituted C 1 -C 30 heteroalkyl, substituted or unsubstituted C 2 -C 30 heterocycloalkyl, substituted or unsubstituted C 5 -C 30 heteroaryl, or substituted or unsubstituted C 5 -C 30 heteroaralkyl, with the proviso that R 2 and R 3 , or R 3 and R 4 , or R 4 and R 5 are optionally joined together to form a ring having one or more atoms selected from the group consisting of C, O, and N, L is a chemical bond, substituted or unsubstituted C 1 -C 30 alkylene, substituted or unsubstituted C 1 -C 30 heteroalkylene, substituted or unsubstituted C 6 -C 30 arylene, substituted or unsubstituted C 6 -C 30 heteroarylene, —O—, —C(O)—, —C(O)O—, —C(CH 3 ) 2 —, —C(CF 3 ) 2 —, —S— or —SO 2 —, R is substituted or unsubstituted C 1 -C 30 alkylene, substituted or unsubstituted C 3 -C 30 cycloalkylene, substituted or unsubstituted C 6 -C 30 arylene, substituted or unsubstituted C 1 -C 30 heteroalkylene, substituted or unsubstituted C 2 -C 30 heterocycloalkylene, or substituted or unsubstituted C 5 -C 30 heteroarylene, and m is an integer from 1 to 1000.
2. The conductive ink according to claim 1 , wherein R 1 , R 2 , R 3 , R 4 , and R 5 are each independently selected from the group consisting of hydrogen, methyl, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl, t-butyl, n-pentyl, amyl, n-hexyl, 2-ethylhexyl, n-heptyl, octyl, iso-octyl, nonyl, decyl, dodecyl, hexadecyl, octadecyl, docodecyl, cyclopropyl, cyclopentyl, cyclohexyl, allyl, propargyl, acetyl, benzoyl, hydroxyethyl, methoxyethyl, 2-hydroxypropyl, methoxypropyl, aminoethyl, cyanoethyl, mercaptoethyl, chloroethyl, methoxy, ethoxy, butoxy, hexyloxy, phenoxy, methoxyethoxyethyl, methoxyethoxyethoxyethyl, imidazolyl, carboxymethyl, trimethoxysilylpropyl, triethoxysilylpropyl, phenyl, methoxyphenyl, cyanophenyl, tolyl, and benzyl.
3. The conductive ink according to claim 1 , wherein the benzoxazine-based compound is selected from structures represented by the following Formulas 2-1 to 2-13:
wherein each R c represents a cardanol-based alkyl and each R u is an urushiol-based alkyl.
4. The conductive ink according to claim 1 , wherein at least one of R 2 , R 3 , R 4 , and R 5 is a hydrocarbon group containing one or more double bonds.
5. The conductive ink according to claim 1 , wherein the metal precursor compounds are metal carboxylates.
6. The conductive ink according to claim 1 , wherein the metal precursor compounds are metal salts of fatty acids.
7. The conductive ink according to claim 5 , wherein the metal of the metal carboxylates is silver (Ag) or gold (Au).
8. The conductive ink according to claim 1 , further comprising one or more additives selected from the group consisting of solvents, complexing agents, resins, stabilizers, dispersants, reducing agents, coupling agents, leveling agents, surfactants, wetting agents, thickeners, and thixotropic agents.
9. The conductive ink according to claim 1 , wherein the viscosity of the conductive ink is adjusted to the range of 0.1 to 50 cPs, as measured at room temperature 20° C., for inkjet printing.
10. A conductive ink in the form of a hybrid ink produced by mixing or reacting the conductive ink according to claim 8 , further comprising one or more materials selected from the group consisting of metal powders, metal oxides, metal nanoparticles, metal wires, conductive polymers, and inks produced therefrom.
11. The conductive ink according to claim 1 , wherein the conductive ink has a viscosity in the range of 1 to 100,000 cPs, as measured at room temperature 20° C.
12. A conductive thin film formed by deposition of the conductive ink according to claim 1 .
13. The conductive thin film according to claim 12 , wherein the conductive thin film comprises a polymer of the benzoxazine-based compound contained in the conductive ink.