IP Library Granted Patent US 9,819,057
Granted Patent B2
US 9,819,057 · App. 13/830,119 · Granted Nov 14, 2017

Rechargeable lithium battery

Inventors: Seung Bum Suh (Yongin-si, KR); Ho-Seok Yang (Yongin-si, KR); Maeng-Eun Lee (Yongin-si, KR); Dai-In Park (Yongin-si, KR); Jee-Won Kang (Yongin-si, KR); Jin-Hyunk Lim (Yongin-si, KR); Hee-Yeon Hwang (Yongin-si, KR); Yun-Hee Kim (Yongin-si, KR); Kyeong-Beom Cheong (Yongin-si, KR); Seon-Hong Lee (Yongin-si, KR); Ho-Gon You (Yongin-si, KR); Alexey Kashaev (Yongin-si, KR); Dae-Yup Shin (Yongin-si, KR)
Assignee: Samsung SDI Co., Ltd.
H01M10/4235H01M10/0567H01M4/62H01M10/052H01M2300/0042
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Quick Facts
Patent No.
US 9,819,057
App. No.
13/830,119
Granted
Nov 14, 2017
Kind
B2
Abstract

A rechargeable lithium battery includes a compound represented by Chemical Formula 1: In Chemical Formula 1, each of k, l, and m is independently an integer of 0 to 20, n is an integer of 1 to 7, and k, l and m are selected such that the compound of Chemical Formula 1 has an asymmetrical structure. The compound of Chemical Formula 1 may be included in the positive electrode, the negative electrode, or the electrolyte of the rechargeable lithium battery.

Claims (38)

1. A rechargeable lithium battery, comprising:

a positive electrode;

a negative electrode;

an electrolyte; and

a compound represented by Chemical Formula 1 in at least one of the positive electrode, the negative electrode or the electrolyte:

 wherein:

each of k, l and m is independently an integer of 0 to 20, and each of k, l and m are different from each other such that the compound of Chemical Formula 1 has an asymmetric structure, and

n is an integer of 1 to 7; and

wherein the compound represented by Chemical Formula 1 is present in the positive electrode, the negative electrode or the electrolyte in an amount of about 0.1 to about 10% based on a total weight of the positive electrode, the negative electrode or the electrolyte in which the compound represented by Chemical Formula 1 is present.

2. The rechargeable lithium battery of claim 1 , wherein n is an integer of 1 to 5, and k, l and m are independently integers of 0 to 10.

3. The rechargeable lithium battery of claim 1 , wherein n is an integer of 1 to 3, and k, l and m are independently integers of 0 to 7.

4. The rechargeable lithium battery of claim 1 , wherein n is 1 or 2, k is 0, and l and m are independently integers of 1 to 5.

5. The rechargeable lithium battery of claim 1 , wherein the compound represented by Chemical Formula 1 is 1,3,6-Hexane Tri-Cyanide (1,3,6-tricyanohexane; 1,3,6-HTCN) or 1,2,6-Hexane Tri-Cyanide (1,2,6-tricyanohexane; 1,2,6-HTCN).

6. An electrode composition, comprising:

an electrode active material; and

a compound represented by Chemical Formula 1:

 wherein:

each of k, l and m is independently an integer of 0 to 20, and each has a different value from the other; and k, l and m are selected such that the compound of Chemical Formula 1 has an asymmetric structure, and

n is an integer of 1 to 7, and

wherein the compound represented by Chemical Formula 1 is present in the electrode composition in an amount of about 0.1 to about 10% based on a total weight of the electrode composition.

7. The electrode composition of claim 6 , wherein the electrode active material is a positive active material.

8. The electrode composition of claim 6 , wherein the electrode active material is a negative active material.

9. The electrode composition of claim 6 , wherein n is an integer of 1 to 5, and k, l and m are independently integers of 0 to 10.

10. The electrode composition of claim 6 , wherein n is an integer of 1 to 3, and k, l and m are independently integers of 0 to 7.

11. The electrode composition of claim 6 , wherein n is 1 or 2, k is 0, and l and m are independently integers of 1 to 5.

12. The electrode composition of claim 6 , wherein the compound represented by Chemical Formula 1 is 1,3,6-Hexane Tri-Cyanide (1,3,6-tricyanohexane; 1,3,6-HTCN) or 1,2,6-Hexane Tri-Cyanide (1,2,6-tricyanohexane; 1,2,6-HTCN).

13. An electrolyte composition, comprising:

a solvent;

a lithium salt; and

a compound represented by Chemical Formula 1:

 wherein:

each of k, l and m is independently an integer of 0 to 20, and each of k, l and m are different from each other such that the compound of Chemical Formula 1 has an asymmetric structure, and

n is an integer of 1 to 7, and

wherein the compound represented by Chemical Formula 1 is present in the electrolyte composition in an amount of about 0.1 to about 10% based on a total weight of the electrolyte composition.

14. The electrolyte composition of claim 13 , wherein n is an integer of 1 to 5, and k, l and m are independently integers of 0 to 10.

15. The electrolyte composition of claim 13 , wherein n is an integer of 1 to 3, and k, l and m are independently integers of 0 to 7.

16. The electrolyte composition of claim 13 , wherein n is 1 or 2, k is 0, and l and m are independently integers of 1 to 5.

17. The electrolyte composition of claim 13 , wherein the compound represented by Chemical Formula 1 is 1, 3, 6-Hexane Tri-Cyanide (1,3,6-tricyanohexane; 1, 3, 6-HTCN) or 1, 2, 6-Hexane Tri-Cyanide (1, 2, 6-tricyanohexane; 1, 2, 6-HTCN).

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 31, 2013
From: SUH, SEUNG BUM; YANG, HO-SEOK; LEE, MAENG-EUN; PARK, DAI-IN; KANG, JEE-WON; LIM, JIN-HYUNK; HWANG, HEE-YEON; KIM, YUN-HEE; CHEONG, KYEONG-BEOM; LEE, SEON-HONG; YOU, HO-GON; KASHAEV, ALEXEY; SHIN, DAE-YUP
To: SAMSUNG SDI CO., LTD.
Reel/Frame 030528/0377 →
Continuity (2)
Provisional Application 61698311 · Sep 7, 2012
Related Publication 20140072865A1 · Mar 13, 2014