Membrane fouling reduction using chemical micropumps
Provided are processes of removing particulate fouling from a filtration membrane or for preventing membrane fouling by particulate matter. A process capitalizes on reversal of a naturally occurring diisophoretic particle deposition to actively move particulate material away from a membrane. A process includes placing a microparticle including a salt in proximity to a membrane such that the microparticle creates a gradient generated spontaneous electric field or a gradient generated spontaneous chemiphoretic field in the solvent proximal to the membrane that actively draws charged particles away from the membrane thereby removing charged particulate matter away from the membrane or preventing its deposition.
1. A process of removing deposits on a membrane comprising:
placing a membrane in a solvent comprising a microparticles, said microparticles comprising a salt,
said microparticles housed in a retaining structure positioned within 1000 micrometers from said membrane and said microparticites in contact with said solvent relative to said membrane so as to produce a gradient generated spontaneous electric field or a gradient generated spontaneous chemiphoretic field, said field in said solvent proximal to said membrane;
said electric field removing or preventing deposits of particles on said membrane.
2. The process of claim 1 wherein said salt comprises a cation and an anion, wherein said cation and said anion have different diffusion coefficients in said solvent.
3. The process of claim 2 wherein said anion has a higher diffusion coefficient than said cation.
4. The process of claim 1 wherein said salt is a carbonate.
5. The process of claim 4 wherein said carbonate is selected from the group consisting of CaCO 3 , Na 2 CO 3 , BaCO 3 , H 2 CO 3 , MgCO 3 , Li 2 CO 3 , and K 2 CO 3 .
6. The process of claim 1 wherein said salt is selected from the group consisting of KI, NaCl, LiCl, and KCl.
7. The process of claim 1 wherein said microparticles are housed in a hydrogel.
8. The process of claim 1 wherein said microparticles have a diameter of 1 nanometer to 100 micrometers.
9. The process of claim 1 wherein said microparticles have a diameter of 3 micrometers to 15 micrometers.
10. The process of claim 1 where said solvent is aqueous.
11. The process of claim 1 wherein said membrane is neutral or negatively charged.
12. The process of claim 1 wherein said membrane is negatively charged.
13. The process of claim 1 wherein said membrane comprises a polyamide, cellulose acetate, or combinations thereof.
14. A process of cleaning a reverse osmosis membrane comprising:
placing microparticles, in a solvent contacting said membrane comprising a membrane charge, said microparticles comprising a salt, acid or base, wherein a diffusion coefficient of an ion of said salt matching said membrane charge is greater than a counter ion of said salt, said
said microparticles positioned relative to said membrane so as to produce a gradient generated spontaneous electric field or a gradient generated spontaneous chemiphoretic field, aid field in said solvent proximal to said membrane;
said microparticles housed in a retaining structure placed within 1000 micrometers from aid membrane;
said field removing deposits of particles on said membrane.
15. The process of claim 14 wherein said salt is selected from the group consisting of CaCO 3 , Na 2 CO 3 , BaCO 3 , H 2 CO 3 , MgCO 3 , Li 2 CO 3 , K 2 CO 3 , KI, NaCl , LiCl , and KCl .
16. The process of claim 14 wherein said microparticles remain in said solvent for a period of 1 hour or more.
17. The process of claim 14 wherein at least a portion of said particles have a neutral charge.