IP Library › Granted Patent US 9,833,766
Granted Patent B2
US 9,833,766 · App. 15/308,382 · Granted Dec 5, 2017

Water-absorbing polymer particles

Inventors: Markus Braun (Mannheim, DE); Monica Haag (Ludwigshafen, DE); Stephan Deuerlein (Ludwigshafen, DE)
Assignee: BASF SE
B01J20/261A61L15/24A61L15/60B01J20/267B01J20/28004C08F220/06C08J3/245C08F2/10C08F2222/1026C08J2333/02
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Quick Facts
Patent No.
US 9,833,766
App. No.
15/308,382
Granted
Dec 5, 2017
Kind
B2
Abstract

Crosslinked polymer particles having a) a proportion of particles having a particle size of 150 to 300 μm of at least 20% by weight, b) a free swell rate of the entirety of the polymer particles FSR overall of at least 0.25 g/g·s, c) a difference ΔFSR of at least 0.15, d) a centrifuge retention capacity CRC of at least 25.0 g/g, and e) a permeability of the swollen gel bed SFC of at least 90×10 −7 cm 3 ·s/g are disclosed.

Claims (18)

1. Water-absorbing polymer particles formed from crosslinked polymer chains comprising predominantly polymerized units of at least partly neutralized acrylic acid, characterized by

a) a proportion of particles having a particle size of 150 to 300 μm of at least 20% by weight,

b) a free swell rate of the totality of the polymer particles FSR overall of at least 0.25 g/g·s,

c) a difference ΔFSR of at least 0.15, where ΔFSR is defined as

ΔFSR=FSR 150-300 μm −FSR overall

in which FSR 150-300 μm represents the free swell rate of the polymer particles having a particle size of 150 to 300 μm,

d) a centrifuge retention capacity CRC of at least 25.0 g/g, and

e) a permeability of the swollen gel bed SFC of at least 90×10 −7 cm 3 ·s/g.

2. Polymer particles according to claim 1 , characterized by a proportion of particles having a particle size of 150 to 300 μm of at least 25% by weight.

3. Polymer particles according to claim 1 , characterized by a proportion of particles having a particle size of 150 to 300 μm of at most 80% by weight.

4. Polymer particles according to claim 1 , characterized by a proportion of particles having a particle size of less than 150 μm of at most 5% by weight.

5. Polymer particles according to claim 1 , characterized by a proportion of particles having a particle size of more than 710 μm of at most 5% by weight.

6. Polymer particles according to claim 1 , characterized by a free swell rate of the entirety of the polymer particles FSR overall of at least 0.26 g/g·s.

7. Polymer particles according to claim 1 , characterized by a free swell rate of the polymer particles having a particle size of 150 to 300 μm FSR 150-300 μm of at least 0.35 g/g·s.

8. Polymer particles according to claim 1 , characterized by a free swell rate of the polymer particles having a particle size of 150 to 300 μm FSR 150-300 μm of at least 0.40 g/g·s.

9. Polymer particles according to claim 1 , characterized by a centrifuge retention capacity CRC of at least 26.0 g/g.

10. Polymer particles according to claim 1 , characterized by a permeability of the swollen gel bed SFC of at least 100×10 −7 cm 3 ·s/g.

11. A hygiene article comprising water-absorbing polymer particles according to claim 1 .

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 2, 2016
From: BRAUN, MARKUS ALBERT; HAAG, MONICA; DEUERLEIN, STEPHAN
To: BASF SE
Reel/Frame 040195/0645 →
Priority Claims (1)
EP 14167497 · May 8, 2014 · regional
Continuity (1)
Related Publication 20170050170A1 · Feb 23, 2017