Cathode active material for lithium secondary battery and lithium secondary battery comprising the same
The present invention relates to an anode active material for lithium secondary battery and a lithium secondary battery including the same, and more specifically it relates to an anode active material for lithium secondary battery in which the a lithium ion diffusion path in the primary particles is formed to exhibit specific directivity, and a lithium secondary battery including the same. The cathode active material for lithium secondary battery of the present invention has a lithium ion diffusion path exhibiting specific directivity in the primary particles and the secondary particles, thus not only the conduction velocity of the lithium ion is fast and the lithium ion conductivity is high but also the cycle characteristics are improved as the crystal structure hardly collapses despite repeated charging and discharging.
1. A cathode active material for lithium secondary battery, which is a cathode active material having a layered structure containing a transition metal, and comprises secondary particles formed by aggregation of primary particles, wherein
an aspect ratio of the primary particles is 1 or more, and
an a-axis direction that is a lithium ion diffusion path in the primary particles is formed to be parallel to a longer side of the primary particles,
wherein the a-axis direction exhibits directivity in a center direction of the secondary particles, and
wherein the lithium ion diffusion path in the primary particles is formed in a direction towards a center of the entirety of the particles, such that a lithium ion diffusion path from a surface to a center of the secondary particles has a one-dimensional or two-dimensional tunnel structure.
2. The cathode active material for lithium secondary battery according to claim 1 , wherein the a-axis direction forms an angle of ±40° with a connecting line connecting a surface of the secondary particles with a center of the secondary particles.
3. The cathode active material for lithium secondary battery according to claim 1 , wherein an area occupied by the primary particles having the lithium ion diffusion path, which forms an angle of ±40° with a connecting line connecting a surface of the secondary particles with a center of the secondary particles, is 10% or more of an area of the secondary particles.
4. The cathode active material for lithium secondary battery according to claim 1 , wherein an area occupied by the primary particles having the aspect ratio of 1 or more and the lithium ion diffusion path in the particles formed to be parallel to a major axis of the particles among the primary particles is 40% or more of an area of the secondary particles.
5. The cathode active material for lithium secondary battery according to claim 1 , wherein the secondary particles are represented by the following Formula 1 and a concentration of transition metal is constant in the entire particles:
Li x Ni 1−a−b−c Co a Mn b Me c O 2−y X y <Formula 1>
(in Formula 1, 0.9≦x≦1.15, 0≦a≦0.5, 0≦b≦0.65, 0≦c≦0.15, 0≦y≦0.1, Me is at least one or more elements selected from the group consisting of Al, Mg, B, P, Ti, Si, Zr, Ba, and any combination thereof; and X is at least one or more elements or molecules selected from anions of F, BO 3 , and PO 4 ).
6. A lithium secondary battery comprising the cathode active material for lithium secondary battery according to claim 1 .
7. A lithium secondary battery comprising the cathode active material for lithium secondary battery according to claim 2 .
8. A lithium secondary battery comprising the cathode active material for lithium secondary battery according to claim 3 .
9. A lithium secondary battery comprising the cathode active material for lithium secondary battery according to claim 4 .
10. A lithium secondary battery comprising the cathode active material for lithium secondary battery according to claim 5 .