Compositions comprising lignocellulosic biomass and organic solvent
The present disclosure relates, at least in part, to compositions comprising lignocellulosic biomass and an organic solvent wherein the lignocellulosic biomass comprises 35% or greater of lignin material. The present disclosure relates, at least in part, to compositions comprising lignocellulosic biomass and an organic solvent wherein the lignocellulosic biomass comprises 50% or less of carbohydrate. In certain embodiments the present compositions may have a viscosity of 5000 cps or less.
1. A composition comprising a lignocellulosic biomass and an organic solvent mixture, wherein the lignocellulosic biomass comprises 35% to 66% of lignin material, 18% to 50% of carbohydrate, and 5% to 9% of recalcitrant cellulose that is hydrolyzed to glucose at a rate of less than 10% a day when incubated at 40° C. in the presence of 20 mg cellulase protein per g cellulose substrate, and wherein the organic solvent mixture comprises about less than 80% of an organic solvent and the remainder water.
2. The composition according to claim 1 , wherein the organic solvent mixture comprises about 45-60% of the organic solvent.
3. The composition according to claim 1 , wherein the composition has a viscosity of 5000 cps or less, 3000 cps or less, or 1500 cps or less.
4. The composition according to claim 1 , wherein the weight ratio of solvent to lignocellulosic biomass is from about 10:1 to about 3:1.
5. The composition according to claim 1 , wherein the pH of the composition is from about 1 to about 3.
6. The composition according to claim 1 , wherein the composition comprises from about 1.5% to about 2.5% of an acid, based on the dry weight of the lignocellulosic biomass.
7. The composition according to claim 1 , wherein the lignocellulosic biomass comprises softwood feedstock.
8. The composition according to claim 1 , wherein the organic solvent is ethanol, methanol, propanol, or a combination thereof.
9. The composition according to claim 1 , wherein the organic solvent mixture is an ethanol/water mixture.
10. A process comprising:
i. obtaining a composition according to claim 1 ;
ii. subjecting the composition to an elevated temperature and an elevated pressure, and optionally adding an acid;
iii. maintaining the elevated temperature and the elevated pressure for a period of time; and
iv. recovering aromatic compounds from the solvent.
11. The process according to claim 10 wherein the process is a continuous process.
12. The process according to claim 10 wherein the elevated temperature is about 180° C. or greater.
13. The process according to claim 10 wherein the elevated pressure is about 1 bar or greater.
14. The process according to claim 10 wherein the elevated pressure is about 35 bar or less.
15. The process according to claim 10 wherein the period of time is 30 minutes or longer.
16. The process according to claim 10 wherein the elevated temperature is about 140° C. to about 165° C. and the period of time is about 30 minutes to about 150 minutes.
17. The process according to claim 10 wherein the elevated pressure is about 18 bar or less.